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de Aguiar Guilherme Carletti,Batalha Daniel Carreira,Fajardo Humberto Vieira,Filho José Balena Gabriel,Bruziquesi Carlos Giovanni Oliveira,de Oliveira Luiz Carlos Alves,Gonçalves Mateus Aquino,Ramalho 한국화학공학회 2023 Korean Journal of Chemical Engineering Vol.40 No.10
In this work, the application of a new, synthesized niobium-based catalyst, called S4 (niobium oxyhydroxide), in the liquid-phase oxidation of methyl-phenyl sulfide (thioanisole) using hydrogen peroxide as oxidant was proposed. The synthetic method employed provided a material with low crystallinity and high specific surface area and acidity. A commercial material, called HY-340 (hydrated niobium oxide), was also employed as heterogeneous catalyst for comparative purposes. The results showed that the synthesized S4 material is an outstanding catalyst, being able to completely convert the substrate (thioanisole) that achieves almost 90% of selectivity for methyl phenyl sulfone formation, under mild reaction conditions. According to the theoretical and experimental combined results, the superior performance of S4 catalyst is related to the better interaction of H2O2 and thioanisole molecules with S4 surface, compared to HY-340, pointing to the greater ability of this catalyst to form reactive oxygen species in contact with hydrogen peroxide, due to its higher content of free hydroxyl groups present on its surface.
Alveolar ridge augmentation with the perforated and nonperforated bone grafts
de Avila, Erica Dorigatti,Filho, Jose Scarso,de Oliveira Ramalho, Lizete Toledo,Real Gabrielli, Mario Francisco,Pereira Filho, Valfrido Antonio Korean Academy of Periodontology 2014 Journal of Periodontal & Implant Science Vol.44 No.1
Purpose: Autogenous bones are frequently used because of their lack of antigenicity, but good osteoconductive and osteoinductive properties. This study evaluated the biological behavior of perforated and nonperforated cortical block bone grafts. Methods: Ten nonsmoking patients who required treatment due to severe resorption of the alveolar process and subsequent implant installation were included in the study. The inclusion criteria was loss of one or more teeth; the presence of atrophy of the alveolar process with the indication of reconstruction procedures to allow rehabilitation with dental implants; and the absence of systemic disease, local infection, or inflammation. The patients were randomly divided into two groups based on whether they received a perforated (inner surface) or nonperforated graft. After a 6-month healing period, a biopsy was performed and osseointegrated implants were installed in the same procedure. Results: Fibrous connective tissue was evident at the interface in patients who received nonperforated grafts. However, full union between the graft and host bed was visible in those who had received a perforated graft. Conclusions: We found that cortical inner side perforations at donor sites increased the surface area and opened the medullary cavity. Our results indicate an increased rate of graft incorporation in patients who received such perforated grafts.
Alveolar ridge augmentation with the perforated and nonperforated bone grafts
Erica Dorigatti de Avila,José Scarso Filho,Lizete Toledo de Oliveira Ramalho,Mario Francisco Real Gabrielli,Valfrido Antônio Pereira Filho 대한치주과학회 2014 Journal of Periodontal & Implant Science Vol.44 No.1
Purpose: Autogenous bones are frequently used because of their lack of antigenicity, butgood osteoconductive and osteoinductive properties. This study evaluated the biologicalbehavior of perforated and nonperforated cortical block bone grafts. Methods: Ten nonsmoking patients who required treatment due to severe resorption of thealveolar process and subsequent implant installation were included in the study. The inclusioncriteria was loss of one or more teeth; the presence of atrophy of the alveolar processwith the indication of reconstruction procedures to allow rehabilitation with dental implants;and the absence of systemic disease, local infection, or inflammation. The patientswere randomly divided into two groups based on whether they received a perforated (innersurface) or nonperforated graft. After a 6-month healing period, a biopsy was performedand osseointegrated implants were installed in the same procedure. Results: Fibrous connective tissue was evident at the interface in patients who receivednonperforated grafts. However, full union between the graft and host bed was visible inthose who had received a perforated graft. Conclusions: We found that cortical inner side perforations at donor sites increased thesurface area and opened the medullary cavity. Our results indicate an increased rate ofgraft incorporation in patients who received such perforated grafts.