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Guangdong Zhou,BoWu,Zhiling Li,Zhijun Xiao,Shuhui Li,Ping Li 한국물리학회 2015 Current Applied Physics Vol.15 No.3
A non-volatile flash memory device based on metal oxide semiconductor (MOS) capacitor structure hasbeen fabricated using platinum nano-crystals(PteNCs) as storage units embedded in HfAlOx high-ktunneling layers. Its memory characteristics and tunneling mechanism are characterized by capacitanceevoltage(CeV) and flat-band voltage-time(ΔVFB-T) measurements. A 6.5 V flat-band voltage(memory window) corresponding to the stored charge density of 2.29 × 1013 cm-2 and about 88% storedelectron reserved after apply ±8 V program or erase voltage for 105 s at high frequency of 1 MHz wasdemonstrated. Investigation of leakage currentevoltage(JeV) indicated that defects-enhanced Pool-Frenkel tunneling plays an important role in the tunneling mechanism for the storage charges. Hence,the PteNCs and HfAlOx based MOS structure has a promising application in non-volatile flash memorydevices.
Zhen Zhou,Zhichao Wu,Zhiwei Wang,Shujuan Tang,Guowei Gu,Luochun Wang,Yingjun Wang,Zhiling Xin 한국화학공학회 2011 Korean Journal of Chemical Engineering Vol.28 No.5
As a modified configuration of the conventional anaerobic/anoxic/aerobic (AAO) process, a novel anoxic/anaerobic/aerobic (Reversed AAO, RAAO) process has been extensively applied in domestic wastewater treatment plants (WWTP). In this study, the Activated Sludge Model No. 2d (ASM2d) and a secondary clarifier model were calibrated and applied to simulate a pilot-scale RAAO test and evaluate the operational performance of the RAAO process. For calibration of the biological model ASM2d, only four kinetic parameters were adjusted to accurately simulate in-process variations of ammonium, nitrate and phosphate. Simulation results by the calibrated model demonstrated that phosphorus accumulating organisms (PAO) in the RAAO process (0.243 gP·(gCOD)^−1) contains less poly-phosphate than the AAO process (0.266 gP·(gCOD)^−1). With the increasing mixed liquor recirculation ratio in the RAAO process,the fraction of heterotrophic biomass and autotrophic biomass both increased, whereas the PAO decreased owing to adverse effects of electron acceptors on phosphorus release and poly-hydroxy-alkanoates synthesis.
Tao Wan,Wenzhong Cheng,Zhiling Zhou,Min Xu,Chuzhang Zou,Ruixiang Li 한국화학공학회 2015 Korean Journal of Chemical Engineering Vol.32 No.7
A new hectorite/poly(acrylamide/itaconic acid) nanocomposite hydrogel was synthesized by inverse microemulsion polymerization. The effects of crosslinker amount on water absorbency and salt absorbency, swellability, pHsensitivity, gel strength, temperature-and shear-resistance were investigated. Water and salt absorbencies, pH-sensitivity and swellability decreased, while gel strength and temperature-and shear-resistance increased with increasing crosslinker amount. Nanocomposite hydrogels had good thermal stability with onset decomposing temperature of 252 oC. The as-synthesized hydrogel particles were regular and spherical-like and had an average particle size of 43 nm in the range of 30-65 nm. Hectorite clay platelets were exfoliated and transformed into amorphous structure.