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Enhanced Formaldehyde Gas Sensing Properties of ZnO Nanosheets Modified with Graphene
Ziwei Chen,Yuyuan Hong,Zhidong Lin,Li-Ming Liu,Xiao-Wen Zhang 대한금속·재료학회 2017 ELECTRONIC MATERIALS LETTERS Vol.13 No.3
In this study, pure ZnO (ZnO-1, ZnO-2) with two different morphologies, andgraphene doped ZnO-2 (G-ZnO-2) were synthesized using a simplehydrothermal process at 150 °C. The formaldehyde gas sensing performanceof the G-ZnO-2 composite, synthesized by an in-situ method was investigated. The morphologies and the structures of the nanomaterials were characterizedby X-ray diffraction, field emission scanning electronic microscopy, andtransmission electron microscopy. The experimental results indicate that the GZnO-2 based sensor exhibits unique advantages for the sensing offormaldehyde gas at concentrations in the range of 2 to 2000 ppm, such as fastresponse/recovery time and good selectivity, at an optimal workingtemperature of 200 °C. The improved sensing performance of the G-ZnO-2composite indicates that the addition of graphene is effective in improving theformaldehyde sensing performance of ZnO-based sensors.
Effect of Gas Sensing Properties by Sn-Rh Codoped ZnO Nanosheets
Ziwei Chen,Zhidong Lin,Mengying Xu,Yuyuan Hong,Na Li,Ping Fu,Ze Chen 대한금속·재료학회 2016 ELECTRONIC MATERIALS LETTERS Vol.12 No.3
The hierarchically porous Sn-Rh codoped ZnO, Sn-doped ZnO and pureZnO nanosheets have been successfully synthesized through a simplehydrothermal reaction process without any surfactant or template at 180°C. The morphology and composition were carefully characterized by X-raydiffraction, energy dispersive X-ray spectrometer, field emission scanningelectronic microscopy and BET. The gas-sensing testing results indicatedthat the Sn-Rh codoped ZnO nanosheets, with the specific surface area was26.9 m2/g, exhibited enhanced gas-sensing performance compared withthat of pure ZnO and Sn-doped ZnO. The high sensitivity of the sensorbased on Sn-Rh codoped ZnO was 149.38 to 100 ppm ethanol and thedetection limit was less than 5 ppm (5.8). The response and recovery timeswere measured to be ~3 s and ~10 s when exposed to 100 ppm ethanol atthe test temperature of 300°C. The good sensing performance of the Sn-Rhcodoped ZnO sensor indicated that hierarchically porous Sn-Rh codopedZnO could be a promising candidate for highly sensitive gas sensors.