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        Pyramid-like CdS nanoparticles grown on porous TiO<sub>2</sub> monolith: An advanced photocatalyst for H<sub>2</sub> production

        Du, Jimin,Wang, Huiming,Yang, Mengke,Li, Kaidi,Zhao, Lixin,Zhao, Guoyan,Li, Sujuan,Gu, Xiaolei,Zhou, Yalan,Wang, Le,Gao, Yating,Wang, Weimin,Kang, Dae Joon Pergamon Press 2017 Electrochimica Acta Vol. No.

        <P><B>Abstract</B></P> <P>Efficient production of H<SUB>2</SUB> via solar-light-driven water splitting by a semiconductor-based photocatalyst without noble metals is crucial owing to increasingly severe global energy and environmental issues. However, many challenges, including the low efficiency of H<SUB>2</SUB> evolution, low solar light absorption, excited electron–hole pair recombination, and slow transport of photoexcited carriers, must be resolved to enhance the H<SUB>2</SUB> photoproduction efficiency and photocatalyst stability. Here, a two-step method is used to synthesize advanced H<SUB>2</SUB>-generating photocatalysts consisting of pyramid-like CdS nanoparticles grown on a porous TiO<SUB>2</SUB> monolith, which show promising photocatalytic activity for the hydrogen evolution reaction. Furthermore, the stability of the photocatalysts is examined through long-term tests to verify their good durability. Without noble metals as cocatalysts, the photocatalyst can reach a high H<SUB>2</SUB> production rate of 1048.7μmolh<SUP>−1</SUP> g<SUP>−1</SUP> under UV–vis irradiation when the ratio of the CdS nanoparticles to TiO<SUB>2</SUB> is 5mol%. This unusual photocatalytic activity arises from the wide-region light adsorption due to the narrow band gap of CdS, effective separation of electrons and holes due to conduction band alignment at the CdS–TiO<SUB>2</SUB> interface, and favorable reaction sites resulting from the porous structure.</P>

      • KCI등재

        Controlled Synthesis of FeSe2 Nanoflakes Toward Advanced Sodium Storage Behavior Integrated with Ether-Based Electrolyte

        Yalan Chen,Jingtong Zhang,Haijun Liu,Zhaojie Wang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.12

        Sodium ion batteries based on the more sodium source reserve than that of lithium have been designed as promising alternatives to lithium ion batteries. However, several problems including unsatisfied specific capacity and serious cyclic stability must be solved before the reality. One of the effective approaches to solve the abovementioned problems is to search for suitable anode materials. In this work, we designed and prepared FeSe2 nanoflakes via a simple hydrothermal method which can be adjusted in composition by Fe precursor. As a potential anode for sodium storage, the optimized FeSe2 electrode was further evaluated in different electrolytes of NaClO4 in propylene carbonate/fluoroethylene carbonate and NaCF3SO3 in diethylene glycol dimethyl ether. The capacity was about 470 mA h g-1 and 535 mA h g -1 at 0.5 Ag-1, respectively, in the voltage between 0.5V and 2.9V in the cycle of stabilization phase. Superior performance both in capacity and in stability was obtained in ether-based electrolyte, which affords the property without plugging the intermediates of transition metal dichalcogenides during charge/discharge processes.

      • KCI등재

        Recombinant Kluyveromyces lactis expressing highly pathogenic porcine reproductive and respiratory syndrome virus GP5 elicits mucosal and cell-mediated immune responses in mice

        Haiyan Zhao,Yalan Wang,Zhitao Ma,Yongqiang Wang,Wen-hai Feng 대한수의학회 2014 Journal of Veterinary Science Vol.15 No.2

        Currently, killed-virus and modified-live porcinereproductive and respiratory syndrome virus (PRRSV)vaccines are used to control porcine reproductive andrespiratory syndrome. However, both types of vaccines haveinherent drawbacks; accordingly, the development of novelPRRSV vaccines is urgently needed. Previous studies havesuggested that yeast possesses adjuvant activities, and it hasbeen used as an expression vehicle to elicit immune responsesto foreign antigens. In this report, recombinantKluyveromyces lactis expressing GP5 of HP-PRRSV(Yeast-GP5) was generated and immune responses to thisconstruct were analyzed in mice. Intestinal mucosalPRRSV-specific sIgA antibody and higher levels of IFN-γ inspleen CD4+ and CD8+ T cells were induced by oraladministration of Yeast-GP5. Additionally, Yeast-GP5administered subcutaneously evoked vigorous cell-mediatedimmunity, and PRRSV-specific lymphocyte proliferationand IFN-γ secretion were detected in the splenocytes of mice. These results suggest that Yeast-GP5 has the potential foruse as a vaccine for PRRSV in the future.

      • SCIESCOPUSKCI등재

        Experiment and modeling of liquid-phase flow in a venturi tube using stereoscopic PIV

        Song, Yuchen,Shentu, Yunqi,Qian, Yalan,Yin, Junlian,Wang, Dezhong Korean Nuclear Society 2021 Nuclear Engineering and Technology Vol.53 No.1

        Venturi tube is based on turbulent flow, whereby the microbubbles can be generated by the turbulent fragmentation. This phenomenon is common in several venturi bubblers used by the nuclear, aerospace and chemical industries. The first objective of this paper is to study the liquid-phase velocity field experimentally and develop correlations for the turbulent quantities. The second objective is to research velocity field characteristics theoretically. Stereoscopic PIV measurements for the velocity field have been analyzed and utilized to develop the turbulent kinetic energy in the venturi tube. The tracking properties of the tracer particles have been verified enough for us to analyze the turbulence field. The turbulence kinetic energy has a bimodal distribution trend. Also, the results of turbulence intensity along the horizontal direction is gradually uniform along the downstream. Both the mean velocity and the fluctuation velocity are proportional to the Reynolds number. Besides, the distribution trend of the mean velocity and the velocity fluctuation can be determined by the geometric parameters of the venturi tube. An analytical function model for the flow field has been developed to obtain the approximate analytical solutions. Good agreement is observed between the model predictions and experimental data.

      • KCI등재

        Highly Efficient Photocatalysts Based on Lamellar-Shaped Bi2S3 Grown on TiO2 Monolith

        Kaidi Li,Fangfang Zhang,Huiming Wang,Yalan Zhou,Lixin Zhao,Jimin Du,Yating Gao,Weimin Wang,강대준 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.09

        Here, the lamellar-shaped Bi2S3 grown on a porous TiO2 monolith was obtained by a two-step method including a sol–gel route and hydrothermal treatment. The photocatalytic activity of the as-synthesized Bi2S3/TiO2 composites was evaluated for photodegradation of methylene blue (MB) dye in aqueous solution under the visible-light irradiation. Based on our experimental results, 5% (molar ratio of Bi2S3 to TiO2) Bi2S3/TiO2 photocatalysts exhibited a maximum photodegradation rate of MB up to 96.9% under visible-light irradiation for 120 min. Our findings indicated that the lamellar-shaped Bi2S3 can extend the light absorption up to visible areas, and porous TiO2 can provide enhanced specific surface area and more mass transfer pathway to enhance the photodegradation efficiency. Furthermore, porous TiO2 can accept the electrons from the Bi2S3 conduction band due to the relatively positive electrode potential to impede the photoproduced electron and hole combination to result in advanced photocatalytic performance.

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