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        Superwetting TiO2-decorated single-walled carbon nanotube composite membrane for highly efficient oil-in-water emulsion separation

        Yahong Sun,Ruiguang Zhao,Quanyong Wang,Yuanyuan Zheng,Gongrang Li,Dejun Sun,Tao Wu,Yujiang Li 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.11

        With the advantages of one-dimensional hollow structure, high porosity and prominent mechanical strength, single-walled carbon nanotubes (SWCNTs) have been extensively utilized to improve conventional filtration membranes for oil/water separation. Their intrinsic hydrophobicity, however, adversely affects the anti-fouling performance of the SWCNT membrane. Herein, a super-hydrophilic and underwater super-oleophobic hierarchical modified membrane with enhanced permeability and anti-fouling property was fabricated using the vacuum-assisted filtration technique by synergistically assembling SWCNTs and titanium dioxide (TiO2) nanoparticles on a cellulose acetate membrane. Highly dispersed SWCNTs were obtained by carboxylating treatment of agglomerate SWCNTs. The controlled stacking of SWCNTs fibers and a controllable amount of TiO2 rendered a modified membrane with high porosity and hierarchical structure, leading to an ultrahigh water flux up to 4,777.07 L·m2·h1, and excellent separation performance with efficiency greater than 99.47%. Most importantly, the membrane exhibited excellent anti-fouling ability during ten cycles with the aid of the super-wetting property of TiO2 nanoparticles. The results indicated that coating TiO2 nanoparticles on SWCNTs modified the surface topography of the obtained SWCNT/TiO2 membrane, which improved hydrophilicity, permeability and anti-fouling property, manifesting attractive potential applications in oil/water separation.

      • KCI등재

        Flexural Behavior of RC Beams with NSM Prestressed Helical Rib Steel Wire

        Meixiang Zhang,Xiaolin Yang,Yahong Ding,Ping Xu,Bo Sun,Xiaoyi Zhang,Xianggang Zhang 대한토목학회 2023 KSCE Journal of Civil Engineering Vol.27 No.9

        The reinforcement technique of near-surface mounted?NSM?prestressed helical rib steel wire (PHRSW) with wide raw material sources, lower in price and high application value can significantly enhance the flexural behavior of reinforced-concrete (RC) structures. Based on 8 flexural RC beams reinforced with NSM PHRSW, performance of test beams under different groove widths (10 mm, 15 mm and 20 mm) and concrete strengths (C30 and C40) was analyzed, including load-deflection, ductility, flexural capacity, strain of longitudinal steel bar and HRSW, failure mode and crack propagation. The results show that the overall flexural behavior RC beams reinforced with NSM PHRSW was significantly improved. There is a good entirety bearing capacity between the longitudinal reinforcement and PHRSW of reinforced beam with suitable groove size. The comprehensive performance of reinforced beams increases first then decreases, with the increase of groove size. The higher the strength of concrete, the more significant the influence of groove size. There is an optimal match between groove width and concrete strength for RC beams reinforced with NSM PHRSW. Considering comprehensive property of reinforced beams, groove width with 15mmwas best in this research. The results can make the research of RC beams reinforced with NSM PHRSW more comprehensive and in-depth, and provide design basis for its engineering application.

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