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The effects of oxygen vacancies on the electrical properties of W, Ti doped CaBi2Nb2O9 piezoceramics
Xinghe Xing,Feng Cao,Zhihang Peng,Yang Xiang 한국물리학회 2018 Current Applied Physics Vol.18 No.10
Different type doped CaBi2Nb2O9 (CBN) ceramics were prepared by a conventional solid state sintering method. The number of oxygen vacancies were decreased or increased by the introduction of W6+ and Ti4+ doping in CBN ceramics. The influence of W6+, Ti4+ and W6+/Ti4+ dopants on the microstructures and electrical properties of CBN-based ceramics was investigated. The voids and spherical morphology in the SEM image of W, Ti co-doped ceramics indicate that W, Ti co-doping could change the microstructure of CBN-based ceramics. Impedance analysis results show that the electrical properties of CBN-based ceramics have a close relationship with the number of oxygen vacancies. W doping and W, Ti co-doping decrease the oxygen vacancies, as a result, the resistance and piezoelectric properties were increased and the frequency dispersion of dielectric properties were restrained.