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Efficient production of propylene and gasoline from methanol in multi-regime riser
Xiaojing Meng,Huiwen Huang,Qiang Zhang,Chunyi Li,Qiukai Cui 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.4
High gas-solid contact efficiency and low solid back-mixing are necessary to both promote methanol conversion and inhibit side reactions. Thus, a novel multi-regime reactor with dense-phase reaction section and dilutephase conveying region was designed. The reactor promoted stable reaction activity during a 300 h pilot-scale evaluation with high yields of propylene and gasoline. A process for maximum propylene and gasoline production from methanol (PGFM) characterized by moderate operating severity, application of ZSM-11 catalyst and novel reactor, and stratified reprocessing or etherification of light gasoline and C4 olefins was proposed. The PGFM process can be implemented in the existing FCC process and is considered to be more economic and flexible.
Conversion of methanol into light olefins over ZSM-11 catalyst in a circulating fluidized-bed unit
Xiaojing Meng,Huiwen Huang,Qiang Zhang,Minxiu Zhang,Chunyi Li,Qiukai Cui 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.3
Methanol conversion and the reaction pathway were investigated in a pilot-scale circulating fluidized-bed (CFB) unit over hierarchical ZSM-11 catalyst. Experimental results indicated that ZSM-11 catalyst was highly resistant to external coke due to the formation of mesopores. Elevated temperatures favored the production of propylene and butylene and decreased the yield of ethylene. Additionally, no direct relations were shown between the formation of ethylene and other products under different pressures, suggesting that ethylene was a primary product produced at the initial of the reaction. Methylation-cracking and oligomerization were verified as the main reaction pathway for the formation of C3 + alkenes., Methylation and oligomerization of olefins were dominated under high methanol partial pressure and consequently responsible for the production of higher olefins, while the b-scission of C7 = for propene and butylene, and C8 = for butylene were enhanced at low methanol partial pressure.
TsMIP6 enhances the tolerance of transgenic rice to salt stress and interacts with target proteins
Linlin Sun,Guohong Yu,Xiaori Han,Shichao Xin,Xiaojing Qiang,Linlin Jiang,Shuhui Zhang,Xian-guo Cheng 한국식물학회 2015 Journal of Plant Biology Vol.58 No.5
Aquaporins (AQPs), a large family of channel proteins in plants, play an important role in regulating the balance of osmotic potential in cells. We isolated an AQP gene, TsMIP6, from the halophyte Thellungiella salsuginea and functionally characterized it in transgenic rice (Oryza sativa). This gene belongs to a subfamily of tonoplast intrinsic proteins and is localized at the plasma membrane. Real-time PCR showed that expression of TsMIP6 in shoots or roots of T. salsuginea was markedly induced by salinity, whereas its ectopic expression in ‘Kitaake’ lines of rice significantly increased plant tolerance to salt stress. Physiological data suggested that TsMIP6 is involved in regulating ion homeostasis and water channel activity in salt-stressed transgenic rice. Heterologous expression analysis indicated that TsMIP6 specifically interacts with a member of the glycoside hydrolase family 64 protein #617 in yeast cells. This suggests that the relationship between TsMIP6 and #617 has a crucial role in mediating osmotic balance in plant cells. Moreover, TsMIP6 might help to modulate the transport of some neutral molecules and may function through a pathway regulating solute equilibrium to maintain osmotic potential.