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Xiaohu Luo,Bo Chen,Ji Li,Bang Lan,Chenliang Zhou,Zhengxing Ren,Chenggang Ci,Yali Liu 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.124 No.-
Herein, we report a rational design and synthesis of a highly-efficient and eco-friendly glucomannanderivative (GA-2) by the introduction of the thiazole and Schiff base groups into glucomannan (GA). After confirmation of GA-2 by the spectroscopic methods, it was introduced as corrosion inhibitor withexcellent anti-corrosion action for mild steel (MS) in the simulated seawater. As-obtained results revealthat GA-2 has a significantly enhanced anticorrosion performance, and its inhibitive efficiency reaches98.8% at the 0.5 mmol L1 inhibitor concentration, much higher than that of GA (69.8%) and the intermediatederivative GA-1 (81.2%). The significantly enhanced protection performance could be attributed tothe rich S heteroatoms, aromatic rings, and Schiff base groups in the GA-2, which strongly promotes thechemisorption as well as physisorption between GAD and MS. X-ray photoelectron spectroscopy (XPS)results, show that the appearance of N-Fe and S-Fe bonds confirms the strongly anchoring interactionbetween GA and MS. Furthermore, according to the quantum chemical calculations, the results fromthe lowe energy gap and radical distribution function (RDF) analyses further confirm the strongchemisorption of GA-2 at the surface of steel, which illustrates the excellent inhibition performance atthe molecule and atom level.
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Nuanyuan Luo,Qunqun Chang,Xiaohu Ren,Peiwu Huang,Wei Liu,Li Zhou,Yungang Liu,Jianjun Liu 대한독성 유전단백체 학회 2020 Molecular & cellular toxicology Vol.16 No.3
Background Trichloroethylene (TCE) is a common industrial solvent and an occupational toxicant. TCE exposure can cause severe hepatotoxicity, but its mode of action is poorly understood. Many studies have shown TCE-induced liver damage in mice, while few have examined the effects of TCE in rats. Objective To explore the effects of TCE in Sprague–Dawley (SD) rats and the potential mechanisms in TCE-induced hepatocytotoxicity. Results The liver index and activities of liver damage marker enzymes (ALT, AST and ALP) in rat serum were elevated along with the increase in TCE dose, while the levels of total proteins and albumin in serum were reduced. The results suggest that TCE is hepatotoxic in rats. 2D-DIGE electrophoresis showed that the levels of 66 liver proteins in TCE-treated rats were abnormally altered (39 up-regulated and 27 down-regulated). In these proteins, six enzymes were related to liver damage and carcinogenesis as indicated by bioinformatics analysis, and Western blot analysis confirmed the alterations of three of them, i.e., aldehyde dehydrogenase 2 (Aldh2), glutathione S-transferase Mu 1 (Gstm1) and peroxisomal bifunctional enzyme (PBE, also named as Ehhadh). PBE was the only protein elevated in a dose dependent manner. Whether PBE can be a biomarker of TCE hepatotoxicity needs to be further studied. Conclusion These findings indicate that TCE induces liver injury in rats.
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