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CHISELED NICKEL HYDROXIDE NANOPLATES GROWTH ON GRAPHENE SHEETS FOR LITHIUM ION BATTERIES
LEI-LEI TIAN,XIAN-YONG WEI,QUAN-CHAO ZHUANG,CHAO WU,RUI-LUN XIE,ZHI-MIN ZONG,YONG-LI CUI,SHI-GANG SUN 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2013 NANO Vol.8 No.6
The morphologies and structures of Ni(OH)2–graphene hybrid materials were tailored by using different mineralizers in this work. It was revealed that the synergic effects of the highly oxidized graphene sheets and the mineralizers played a crucial role in controlling the morphology and structure of the nanocomposites, and Na2CO3 is a very effective mineralizer for growing chiseled 2D nanoplates of Ni(OH)2 on graphene sheets. When produced with NaOH, fragmental Ni(OH)2 crystals with irregular shapes erratically decorated on graphene sheets. In contrast, chiseled Ni(OH)2 hexagonal nanoplates grown on graphene sheets were obtained when Na2CO3 was used as the mineralizer. These unique 2D–2D nanoarchitectures with higher contact area between the nanocrystals and graphene substrate can increase the interfacial interaction and then efficiently improve the structural stability of the composite material, thus exhibiting an enhanced Li storage capacity and excellent cycling performance of 562 mAh g-1 after the 36th cycle.
Xian-Lei Shi,Yongju Chen,Qianqian Hu,Feng Wang,Peigao Duan 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.60 No.-
An efficient, recyclable and large-scalable fiber-supported Fe(III) catalytic system verifed in the one-pot multicomponent Biginelli reactions, is presented. The fiber catalyst was prepared conveniently from commercially available polyacrylonitrile fiber according to a simple two-step procedure by amination and chelation in water, and characterized detailedly with ICP analysis, morphology, mechanical properties, elemental analysis, FTIR spectroscopy, and SEM during the modification and utilization processes. Moreover, the fiber catalyst-mediated reactions showed broad applicability and proceeded smoothly to afford a series of substituted 3,4-dihydropyrimidin-2-(1H)-ones/-thiones (yields 81–94%) in ethanol under mild conditions. Furthermore, the newly developed fiber catalyst held high strength, good flexibility and exhibited excellent stability and recyclability (over 10 cycles), and the procedure was operationally concise and effectively amenable to the gram-scale on a simple fixed-bed reactor with potential industrialization prospect.
Xian-Lei Shi,Yongju Chen,Qianqian Hu,Wenqin Zhang,Chenxu Luo,Peigao Duan 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.53 No.-
A potential industrialized fiber catalyst for “click chemistry” via the one-pot multicomponent Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC) for the synthesis of 1,2,3-triazoles in water, is reported. Detailed characterization by appearance, mechanical properties, elemental analysis, FTIR spectroscopy, and SEM confirmed the rangeability of the fiber catalyst during the preparation and utilization processes. Moreover, the fiber catalyst-mediated reactions proceeded smoothly to afford triazoles with nearly quantitative yields in short time (15 min). Furthermore, the fiber catalyst has shown tandem activities and superior recyclability (over 10 cycles), and the procedure is operationally simple and amenable to the gram-scale on a simple fixed-bed reactor.
Xian-Lei Shi,Qianqian Hu,Yongju Chen,Feng Wang,Peigao Duan 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.65 No.-
An ultra-high performance fiber, serving as a novel material for heterogeneous-acid catalyst for the conversion of biomass components to methyl levulinate, is presented. The catalyst was prepared conveniently from commercially available polyphenylene sulfide fiber by sulfonation, and characterized detailedly by elemental analysis, FTIR spectroscopy, SEM and mechanical strength at different stages. Moreover, the catalyst exhibited higher activity for biomass components transforming into methyl levulinate (52–96%), and prominent ability to be reused with good recyclability and stability. Furthermore, the effective large-scale process with fiber catalyst in impellers of the agitation system is very attractive for the industrial applications.
Lijuan Jiang,Xian-Lei Shi,Yue Lv,Honghui Gong,Shuangshuang Liu,Mengmeng Du,Qianqian Hu,Keren Shi 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.113 No.-
The development of highly efficient, economical and environmentally friendly catalytic systems is ofgreat significance from the green chemistry point of view. In this paper, we presented a succinct approachto create a heterogeneous acid–base bifunctional catalyst for one-pot tandem reaction from the commerciallyavailable textile fiber. The ultra-high strength textile fiber polyetheretherketone (PEEK) was functionalizedby a post-grafting method to combine two antagonistic active functions in a synergisticcatalyst, and the resulting fiber samples were characterized in detail by morphology, mechanical properties,elemental analysis, X-ray photoelectron spectroscopy, inductively coupled plasma-atomic emissionspectrometry, X-ray diffraction, Fourier transform infrared spectroscopy, ultraviolet–visible spectrum,nuclear magnetic resonance spectroscopy and thermogravimetric analysis, and further revealed thatthe amines and the heteropolyacid were immobilized by acid–base interactions in the PEEK surface layerwith sufficient stability. Moreover, the acid–base bifunctional catalyst can be successfully applied in theacceleration of the one-pot tandem deacetalization–Knoevenagel reactions with high-efficiency (lowercatalyst dosage 0.3 mol%, higher product yields 81–92%), whereas the homogeneous catalysts wereunable to initiate the reaction due to their mutual neutralization in solution, and the catalytic mechanismwas elucidated by comparison. Furthermore, the fibrous catalyst could maintain its activities more than10 cycles with a simple post-processing, and the mediated system was capable of enlarging to the gramscale,which are envisaged for industrial operations and cleaner productions.
Qianqian Hu,Xian-Lei Shi,Yongju Chen,Feng Wang,Yujing Weng,Peigao Duan 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.69 No.-
Herein, a newly designed and synthesized fiber-supported polyquaterniums@Cu(I) served as efficient and recyclable polymer-supported copper complex catalysts for alkyne coupling and cycloaddition reactions, is reported. The fiber-supported copper complex catalyst was prepared systematically from commercially available polyacrylonitrile fiber, and characterized detailedly by elemental analysis, FTIR spectroscopy, mechanical properties, and SEM during both of the preparation and utilization processes. Moreover, the fiber-supported polyquaterniums@Cu(I) has been verified to possess high catalytic activities for the homocoupling of terminal alkyne in ethyl acetate (10 samples yields 83–99%, 10 cycles from 98% to 95%), A3 coupling of alkyne, aldehyde and amine in toluene (10 samples yields 81–94%, 10 cycles from 94% to 90%), and click chemistry of CuAAC reactions in water (10 samples yields 82–99%, 21 cycles from 97% to 96%). Furthermore, the newly developed fiber catalyst in spinning basket reactor displayed excellent stability and recyclability, and the concise and effective gram-scalable operation has extensive application prospect on chemical productions.
Qianqian Hu,Xian-Lei Shi,Yongju Chen,Xuefeng Han,Peigao Duan,Wenqin Zhang 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.54 No.-
A universal fiber catalyst for the Knoevenagel condensations is presented. The detailed characterization by mechanical properties, elemental analysis, FTIR spectroscopy, and SEM confirmed the rangeability of the fiber catalyst during the full-course. Moreover, the mediated condensations proceeded smoothly with lower catalyst amount (1 mol%) in different solvents of varying polarities and the products were obtained in good to excellent yields (95–99%), and even with water as the solvent could also achieve a series of a,b-unsaturated compounds with nearly quantitative yields at room temperature. Furthermore, the catalyst exhibited excellent flexibility and could be easily recovered and recycled with prominent stability over 10 cycles, and the procedure was operationally convenient and effectively amenable to the gram scale on a simple fixed-bed reactor.
Pengyu Li,Liwei Mi,Yuanyuan Liu,Wenqin Zhang,Xian-Lei Shi 한국공업화학회 2020 Journal of Industrial and Engineering Chemistry Vol.81 No.-
A series of monofunctional and bifunctional polyacrylonitrilefiber catalysts have been successfullyprepared to catalyze the decarboxylative Doebner–Knoevenagel reaction of aldehydes and monoethylmalonate for the syntheses of the (E)-α,β-unsaturated esters. Among which, the catalyst PANPDFII/I showsthe best synergistic catalytic activity with high yields (89–96%), stereoselectivities (Z:E > 99:1) andreusability (up to 8 times). The influences of the N position on aminopyridine moiety, solvent andtemperature on the catalytic system were investigated in detail. This catalytic system can process well inhigher or lower polar organic solvents instead of moderate polar solvents, which is an interestingphenomenon in organic catalysis, and the reasons are explained in this work. Furthermore, a DMAP (4-dimethylaminopyridine) and piperazine synergistic catalytic mechanism in the micro-environment ofthefiber catalyst has been conceived to explain the high catalytic performance of this catalytic system. Besides, thefiber catalyst PANPDFII/I shows high application potential in industry for its good performancein scaled-up experiment, as well as its advantages of the easy preparation, high mechanical strength,flexibility and high stability in air.