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Study on surface physical and chemical mechanism of nanobubble enhanced flotation of fine graphite
Tang Chongliang,Ma Fangyuan,Wu Tingyu,Zhang Di,Wang Ye,Zhao Tonglin,Fan Zhaolin,Liu Xinyue 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.122 No.-
It has been concluded in a recently published investigation that the nanobubble flotation process significantlyreduces the number of fine flake graphite flotation stages and improves the flotation performance. The present study was conducted to explore the mechanisms of surface nanobubbles enhancing flake graphiteflotation by investigating effects of nanobubbles on surface properties of graphite and interactionsbetween particles and bubbles by use of contact angle analyzer, zeta potential analyzer, FourierTransform Infrared Spectroscopy (FTIR), and X-ray Photoelectron Spectroscopy (XPS). The study resultsshow that nanobubbles can improve the surface properties of graphite and enhance the adsorption effectof collector, which increased the contact angle of the graphite surface by 11.93 compared with conventionalflotation. Infrared spectroscopy and potential analysis showed that the nanobubbles could enhancethe hydrophobic attraction and reduce the electrostatic repulsion between the collector and the graphitesurface, which was beneficial to enhance the hydrophobic surface of the graphite and enhance theagglomeration of fine graphite particles. XPS analysis showed that the nanobubbles covered polar hydrophilicgroups (such as CAO, C@O, COOH) on the graphite surface, which enhanced the adsorption of collectorto improve the hydrophobicity of graphite surface.