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김재광,임두현,Johan Scheers,Jagath Pitawala,Susanne Wilken,Patrik Johansson,안주현,Aleksandar Matic,Per Jacobsson 한국전기화학회 2011 한국전기화학회지 Vol.14 No.2
In this study we have investigated the Li-ion coordination, thermal behavior and electrochemical stability of N-butyl-N-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide (Py_14TFSI) with lithium bis(trifluoromethanesulfony)imide (LiTFSI) doping intended for use as electrolytes for lithium batteries. The ionic conductivity is reduced and glass transition temperature (T_g) increases with LiTFSI doping concentration. Also, the electrochemical stability increases with LiTFSI doping. A high LiTFSI doping could enhance the electrochemical stability of electrolytes for lithium batteries, whereas the decrease in the ionic conductivity limits the capacity of the battery.
Kim, Jae-Kwang,Lim, Du-Hyun,Scheers, Johan,Pitawala, Jagath,Wilken, Susanne,Johansson, Patrik,Ahn, Jou-Hyeon,Matic, Aleksandar,Jacobsson, Per The Korean Electrochemical Society 2011 한국전기화학회지 Vol.14 No.2
In this study we have investigated the Li-ion coordination, thermal behavior and electrochemical stability of N-butyl-N-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide ($Py_{14}TFSI$) with lithium bis(trifluoromethanesulfony)imide (LiTFSI) doping intended for use as electrolytes for lithium batteries. The ionic conductivity is reduced and glass transition temperature ($T_g$) increases with LiTFSI doping concentration. Also, the electrochemical stability increases with LiTFSI doping. A high LiTFSI doping could enhance the electrochemical stability of electrolytes for lithium batteries, whereas the decrease in the ionic conductivity limits the capacity of the battery.