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Sreesai, Siranee,Sthiannopkao, Suthipong Canadian Science Publishing 2009 Canadian journal of civil engineering Vol.36 No.4
<P> Utilization of zeolite industrial wastewater as a sorbent and (or) precipitant to remove Cu and Zn from copper-brass pipe industrial wastewater was conducted. These wastewaters were sampled and values for pH, temperature, biochemical oxygen demand (BOD5), chemical oxygen demand (COD), total solids (TS), total dissolved solids (TDS), total suspended solids (TSS), and heavy metals were determined. In addition, the sorption isotherms of Cu and Zn in copper-brass pipe industrial wastewater onto solids of zeolite industrial wastewater at various dilutions of copper-brass pipe industrial wastewater were explored. The relationship between Cu and Zn concentrations and their removal efficiencies under different conditions of wastewater pH, contact times, and ratios between copper-brass pipe industrial wastewater and zeolite industrial wastewater was examined. Zeolite industrial wastewater contained various carbonate compounds that contributed to high pH and TDS values, and low heavy metals contamination whereas copper-brass pipe industrial wastewater had a low pH value and was contaminated with heavy metals, especially Cu and Zn. Application of zeolite industrial wastewater significantly increased the pH of copper-brass pipe industrial wastewater and consequently removed Cu and Zn. The increase in pH of the wastewater mixture significantly enhanced the heavy metals removal. The Langmuir equation described sorption isotherms of Cu and Zn onto solids of zeolite industrial wastewater at neutral pH (6-7) while the Freundlich equation fitted well at pH @@>@@ 12. The maximum Cu (97%-98%) and Zn (92%-96%) removal efficiencies occurred at the original pH 12.8 of zeolite industrial wastewater, at the ratio of copper-brass pipe industrial wastewater to zeolite industrial wastewater 3:1 (vol.:vol.) and at 30 min contact time. </P>
Sthiannopkao, Suthipong,Sreesai, Siranee Elsevier 2009 Journal of environmental management Vol.90 No.11
<P><B>Abstract</B></P><P>Two pulp and paper industrial wastes, lime mud (LM) and recovery boiler ash (RB), have low moisture contents, low heavy metal contaminations and contain various carbonate compounds which contribute to a high pH. Metal finishing wastewater (MF-WW) has a low pH, high levels of TDS and high contaminations from Cr, Cu, Pb and Zn. The heavy metals from MF-WW were removed by sorption and precipitation mechanisms. LM gave better results in removing heavy metals from MF-WW than RB. At a reaction time of 45min, the maximum removal efficiencies for Cr (93%) and Cu (99%) were obtained at 110gL<SUP>−1</SUP> of LM, but at 80gL<SUP>−1</SUP> for Pb (96%) and Zn (99%). Treatment with LM gives a higher sludge volume than with RB. However, the leachability of heavy metals from LM is lower. Leachability of heavy metals in the sediment for all selected treatment conditions is within government standards.</P>
Titima Koonsom,Duangrat Inthorn,Siranee Sreesai,Paitip Thiravetyan 대한환경공학회 2014 Environmental Engineering Research Vol.19 No.3
The As accumulation in part of roots, shoots, husks and grains of rice plants was significantly decreased with the increasing dosage of kaolin addition from 0.5% to 10% w/w. Kaolin addition could reduce As accumulation in rice plants, which mainly could be attributed to the formation of stable crystalline Al oxides bound As that decreased the available As in soil with decreased As accumulation in rice plants. The pH values of the soils did not change significantly when amended with kaolin. The pH values of the soils was neural that proper to adsorb of arsenic with Al₂O₃. Arsenic tends to adsorb with Al₂O₃ at acid neutral pH and with desorbing at alkaline pH. The dry weight of rice plant was significantly increased with the increasing dosage of kaolin addition from 2.5% to 10% w/w. The highest dry weight of rice plants was 6.67 g/pot achieved at kaolin addition of 10% w/w with about 13% increasing over the control, which was probably attributed to the highest As concentration formation with kaolin at this dosage. The results of this study indicated that kaolin has the potential to reduce As accumulation in rice plants and enhance the dry weight of rice plants.