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Shuling Zhang,Jianxin Mu,Dianfu Ren,Fugui Zhou,Zhenhua Jiang,Zhongwen Wu,Guibin Wang 한국고분자학회 2010 Macromolecular Research Vol.18 No.12
An improvement in the processability of poly(ether ether ketone) (PEEK) and PEEK/carbon fiber (PEEK/CF) composites with less influence on the other properties is important. A novel high temperature lubricant, GENIOPLAST PELLETS (GPPS), was used to decrease the melt viscosity of PEEK and PEEK/CF composites. PEEK/GPPS and PEEK/CF/GPPS compounds were characterized by dynamic rheometry, universal tester, scanning electron microscopy (SEM), thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results showed that a small amount of GPPS could decrease the melt viscosity of the compounds during processing,and improve the dispersion uniformity of the carbon fiber in the PEEK matrix, and further enhance the tensile strength of PEEK/CF composites, but have little effect the thermal stability of the compounds.
Zhenhua Jiang,Xiujie Li,Shuling Zhang,Fugui Zhou,Jinhui Pang,Chunfeng Zhang,Dong Sun,Jianxin Mu,Guibin Wang 한국고분자학회 2011 Macromolecular Research Vol.19 No.5
Hyperbranched poly(ether ether ketone)s (HPEEKs) that were suitable as rheology control agents for linear poly(ether ether ketone)s (LPEEKs) were first prepared via commercially available hydroquinone (A2 monomer,HQ) and synthesized 3,4',5-trifluoro-benzophenone (BB'2 monomer, TF) effortlessly. The polymerization mode of A2 + BB'2 was demonstrated by MS. Moreover, FTIR, 1H NMR, 13C NMR, and 19F NMR spectroscopy revealed the structure and degree of branching (DB) of the resulting polymers. In comparison with A2 + B3 approach, HPEEK prepared using an A2 + BB'2 strategy possessed a higher molecular weight, and improved the melt processability of LPEEK. Remarkably, with the addition of HPEEK, the mechanical properties of LPEEK increased with a HPEEK content of 5%. The improved mechanical properties were attributed to the good miscibility. Moreover, the addition of HPEEK did not decrease the thermal stability of LPEEK.
Silencing of Long Non-Coding RNA MALAT1 Promotes Apoptosis of Glioma Cells
Jianping Xiang,Shifeng Guo,Shuling Jiang,Yuelong Xu,Jiwei Li,Li Li,Jinyu Xiang 대한의학회 2016 Journal of Korean medical science Vol.31 No.5
The metastasis-associated lung adenocarcinoma transcription 1 (MALAT1) is a highly conserved long non-coding RNA (lncRNA) gene. However, little is known about the pathological role of lncRNA MALAT1 in glioma. In the present study, we explored the expression level of lncRNA MALAT1 in primary glioma tissues as well as in U87 and U251 glioma cell lines. Using qRT-PCR, we found that the expression of lncRNA MALAT1 was significantly increased in glioma tissues compared with that of paracancerous tissues. Meanwhile, the expression of MALAT1 was highly expressed in U98 and U251 cells. In order to explore the function of MALAT1, the expression of MALAT1 was greatly reduced in U87 and U251 cells transfected with siRNA specifically targeting MALAT1. Consequently, cell viability of U87 and U251 cells were drastically decreased after the knockdown of MALAT1. Concomitantly, the apoptosis rate of the two cell lines was dramatically increased. Furthermore, the expression levels of some tumor markers were reduced after the knockdown of MALAT1, such as CCND1 and MYC. In summary, the current study indicated a promoting role of MALAT1 in the development of glioma cell.
Lei Lei,Yunhe Zhang,Xiujie Li,Jianxin Mu,Guibin Wang,Zhenhua Jiang,Shuling Zhang 한국고분자학회 2010 Macromolecular Research Vol.18 No.4
A novel hyperbranched poly(aryl ether ketone) terminated with cobalt phthalocyanine (CoPc-T-HPAEK)was prepared using 1,3,5-tris[4-(4-fluorobenzoyl) phenoxy] benzene (B3), as a ‘core’ molecule, 4,4'-(hexafluoroisopropylidene)diphenol (6F-BPA) as an A2 monomer, and cobalt phthalocyanine as an end-capping reagent. CoPc-THPAEK showed good solubility, thermal stability and catalytic activity in the oxidative decomposition of 2,4,6-trichlorophenol (TCP) under H2O2 or KHSO5. Moreover, the oxidative effect of KHSO5 was superior to that of H2O2,and the catalytic activity of CoPc-T-HPAEK was much higher than that of linear poly(aryl ether ketone) terminated with cobalt phthalocyanine (CoPc-T-LPAEK) and linear poly(aryl ether ketone) with a cobalt phthalocyanine pendant unit (CoPc-S-LPAEK).