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Modeling and experimental studies of ammonia absorption in a spray tower
Shichao Ye,Jie Zhu,Zhenhua Liu,Jie Bai,Yunfeng Yang,Qin Peng 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.1
We did an experimental study on ammonia absorption in a spray tower. The kinetic characteristics of droplets were investigated by considering the forces acting on a droplet. The gas-phase mass transfer coefficient was deduced with the Colburn analogy method. A simplified model for predicting NH3 capture with a spray tower has been presented based on mass transfer and ionic equilibrium, which was successfully validated against experimental data. The influences and the sensitivity analysis of main operating parameters on the absorption efficiency were analyzed. As the most sensitive parameter, the mean droplet diameter was obtained by fitting experimental data with an empirical correlation. The distributions of two typical process parameters along the absorber were also simulated. Decreasing the pH value of absorbent is an effective but restrictive way to strengthen the mass transfer rate on account of insufficient liquid-side resistance.
Yingguang Liang,Chunxiang Cui,Hongtao Geng,Lu Liu,Sen Cui,Shichao Yang 대한금속·재료학회 2023 METALS AND MATERIALS International Vol.29 No.4
In this work, as an inoculant, in-situ BaB6/Al composites was fabricated and used to refine the α-Al dendrites and modify theeutectic Si of A356.2(Al–7Si–0.3Mg) alloy. BaB6/Al ingot and ribbon composites mainly contain two phases, α-Al and BaB6. In BaB6/Al ribbons, nano-size BaB6ceramic particles exist and disperse uniformly which help to better exert the inoculanteffect in A356.2 alloy. YS, UTS, EL and HV of B2 alloy are 36.3%, 18.3%, 46.4% and 20.8% higher than the base alloy (B0),respectively. The ductile fracture characteristics are more obvious. Moreover, B2 alloy shows the best corrosion resistance. Aland BaB6form a clear, stable and well matched interface, so BaB6particles can act as the heterogeneous nucleation of α-Aland refine the A356.2 alloy. Furthermore, the combined of free micro-alloying elements Ba and B in BaB6/Al compositespromote the twins formation, which change the eutectic Si to fine fibrous and granular shape.