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        Microstructural Refinement and Performance Improvement of Cast n-Type Bi2Te2.79Se0.21 Ingot by Equal Channel Angular Extrusion

        Xiaoming Hu,Xi’an Fan,Bo Feng,Dong Kong,Peihai Liu,Rusong Li,Yanglin Zhang,Guangqiang Li,Yawei Li 대한금속·재료학회 2021 METALS AND MATERIALS International Vol.27 No.8

        How to form a uniform fine-grained structure in n-type polycrystalline Bi2Te3based alloys to stabilize and improve thethermoelectric properties is the burning issue to be solved. In the present work, equal channel angular extrusion (ECAE)method was used to extrude the cast ingot directly at various temperatures to obtain the BiTeSe polycrystalline bulk alloyswith uniform microstructure. The initial lamellae coarse grains (hundreds microns to several millimeters) were efficiently anduniformly refined to a minimum of 4.07 μm at 703 K, which fully demonstrates the feasibility of grain refinement by ECAEfor cast n-type BiTeSe ingot. The average grain size of the extruded billets rapidly increased from 5.35 to 29.55 μm withthe increase of extrusion temperature from 703 to 823 K. Meanwhile, the behavior of abnormal grain growth became moreevident as the extrusion temperature increased because the growth rate increased more rapidly than the rate of nucleation. As the extrusion temperature increased, the Vickers hardness decreased gradually due to grain coarsening. BiTeSe alloysextruded at 703 K achieved the maximum Vickers hardness of 59.8 HV0.05,which was nearly three times higher than that ofthe initial cast ingot. All extruded BiTeSe billets possessed the much higher dimensionless figure of merit (ZT), comparedwith the initial cast ingot due to the simultaneously optimization of electrical and thermal transport performances caused byECAE process. Finally, the specimen extruded at 823 K achieved the maximum ZT of 0.685 at 383 K.

      • KCI등재

        Carbon-based electrode fabrication and performance of bioelectrochemical anaerobic digestion for sewage sludge

        Qing Feng,Zhengkai An,Rusong Zhao,Xiaoli Wang,Jun Li,송영채 한국마린엔지니어링학회 2019 한국마린엔지니어링학회지 Vol.43 No.10

        Bioelectrochemical anaerobic digestion (BEAD) is a technology which exploits the potential of microorganism by supplying a small amount of electric energy in an anaerobic digester. The electrode material is one of the most important parts of a bioelectrochemical system. For the anodes and cathodes of BEAD process, graphite fiber fabric (GFF), a carbon based material with good biocompatibility and non-corrosive property, was selected and its conductivity was modified by depositing carbon nanotube (CNT) via electrophoresis deposition (EPD) method. In the BEAD process, the organic matter in the reactor is oxidized on the surface of anode forming proton, carbon dioxide and electron. The electron produced is transferred to the cathode due to the potential difference between anode and cathode, followed by methane production on the surface of cathode resulting from the combination of carbon dioxide, electron and proton. The biochemical reactions at the electrodes can be controlled by the electrode potentials. When the potential between anode and cathode was maintained at 0.3 V using an external power supply, the BEAD reactor showed remarkable performance after the start-up period of 40 days. The performance of BEAD reactor was stable in terms of pH (7.2~7.5), alkalinity (4,500~5,200mg/L as CaCO3), methane content in biogas (77.3%) and volatile fatty acid levels (VFA < 250mg HAc/L). During steady state, the specific methane production rate and VS reduction were stabilized at 412 mL CH4/L.d and 72.5%, respectively, which were much higher than the conventional anaerobic digestion. The application of bioelectrochemical technology to anaerobic digestion provides a chance to overcome the disadvantages of conventional anaerobic digestion.

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