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Yihan Ling,Huixin Xie,Zijing Liu,Xiaoni Du,Hui Chen,Xuemei Ou,Ling Zhao,Riyan Achmad Budiman 대한금속·재료학회 2018 ELECTRONIC MATERIALS LETTERS Vol.14 No.4
For the sake of improving the electrochemical activity and chromium tolerance of the K2NiF4- type oxide, La2NiO4+ δ (LNO), with nonnucleation agents like Mn and Sr elements, the electrochemical performance and degradation were comparatively studied at two cathodes La2Ni0.9Fe0.1O4+ δ (LNF) and LNF-40wt%Gd0.1Ce0.9O1.95 (LNF-GDC) on the GDC electrolyte,where 5wt%Cr2O3 incorporation provides Cr-containing atmosphere. Compared with non-doped LNO, LNF shows a higherinterstitial oxygen concentration (δ = 0.298) and a lower electrical conductivity, where bivalent Ni ion, Ni×Ni , and trivalentNi ion, Ni⋅Ni , and trivalent Fe ion on Ni-site, Fe⋅Ni , were observed from the XPS measurements. LNF-GDC shows greatlyreduced interfacial polarization resistances (Rp), which are only half of those of LNF, indicating a better electrochemicalperformance. More importantly, no significant degradation of LNF-GDC in performance has been observed under exposureof Cr-containing atmosphere at 700 °C for 350 h, while Rp of LNF increased by nearly 20%, suggesting LNF by GDCincorporation can enhance the electrochemical performance as well as chromium tolerance for intermediate temperaturesolid oxide fuel cells (IT-SOFCs).