http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Reihaneh Pashmineh Azar,Cavus Falamaki 한국공업화학회 2012 Journal of Industrial and Engineering Chemistry Vol.18 No.2
An Iranian clinoptilolite has been modified with MnO2 for the catalytic removal of Fe2+ cations from water in a batch slurry reactor. The modified zeolite was subjected to FESEM, XRD, WDX, XRF and specific surface area analysis. A correlation for the intrinsic catalytic reaction rate incorporating both Fe2+ and dissolved oxygen concentration as a function of reaction temperature has been presented. The effect of the modified zeolite aggregate particle size on the iron removal kinetics has been investigated. It was shown that for particles larger than 150 mm, diffusion through the mesopores of the zeolite aggregate is rate controlling. The effective diffusion coefficient through the particles at RT has been calculated as 2.3 106 cm2 s1. It is shown that liquid phase molecular diffusion within the mesopores is the dominating mass transfer mechanism.