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High C-rate performance of LiFePO4/carbon nanofibers composite cathode for Li-ion batteries
Adewale A. Adepoju,Quinton L. Williams 한국물리학회 2020 Current Applied Physics Vol.20 No.1
Carbon nanofibers (CNFs) were incorporated into LiFePO4 composite cathode through conventional slurry formulation. Pristine LiFePO4 and modified LiFePO4 cathode samples were characterized by scanning electron microscopy, galvanostatic charge/discharge measurements, and cyclic voltammetry. Electrochemical measurements at room temperature showed LiFePO4/CNF composite to exhibit a higher specific discharge capacity of ~150 mAh g−1 at 0.1C, excellent high rate performance at >5C capability rates, and better cycling stability with 98.4% capacity retention at 5C after 200 cycles. The improved high C-rate performance of the LiFePO4/CNF composite cathode can be attributed to long-range conductive networks formed through bridges created by the CNFs. The enhanced battery performance indicates promise for high-power applications
Synthesis of VO2 (B) nanorods for Li battery application
Ch.V. Subba Reddy,Edwin H. Walker Jr.,S.A. Wicker Sr.,Quinton L. Williams,Rajamohan R. Kalluru 한국물리학회 2009 Current Applied Physics Vol.9 No.6
Vanadium dioxide nanorods were synthesized through a hydrothermal reaction from V2O5 xerogel, poly (vinyl pyrrolidone) (PVP) and lithium perchlorate (LiClO4). The prepared samples were characterized by X-ray diffraction, infrared spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electrochemical discharge–charge cycling in lithium battery. SEM images reveal the nanorods to have dimensions on the order of 1–3 ㎛ in length and 10–50 nm in diameter. The measured initial discharge capacity of the lithium battery with a cathode made of VO2 (B) nanorods was 152 mA h/g. Vanadium dioxide nanorods were synthesized through a hydrothermal reaction from V2O5 xerogel, poly (vinyl pyrrolidone) (PVP) and lithium perchlorate (LiClO4). The prepared samples were characterized by X-ray diffraction, infrared spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electrochemical discharge–charge cycling in lithium battery. SEM images reveal the nanorods to have dimensions on the order of 1–3 ㎛ in length and 10–50 nm in diameter. The measured initial discharge capacity of the lithium battery with a cathode made of VO2 (B) nanorods was 152 mA h/g.