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LU ZHANG,Peihui Yang,YAN-JIE GUO,JIAN-JUN LUO,GUI-MIN SUN,ZHI-HONG LIANG,YAN-JUAN TANG 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2014 NANO Vol.9 No.3
A novel core – shell hybrid nanostructure was constructed by employing gold nanorod (AuNR)combined with rhodamine B (RB) as a core and silica as a shell. The poly(sodium 4-styr-enesulfonate) (PSS), a negatively charged polyelectrolyte, played the role of linker to electro-statically trap RB on AuNRs. Due to the °uorescence spectral overlap between RB and AuNRs at560 nm, the red °uorescence and enhanced green °uorescence of the hybrid nanostructures wereobserved obviously, which is capable for dual-color labeling. To reduce toxic side e®ects ofAuNRs, silica was coated on AuNRs as a shell to fabricate the novel core – shell hybrid nano-structure function as a dual-color labeling for cancer-cell imaging. The fabricated compositestructures were characterized by transmission electron microscopy (TEM), absorption spectrum,°uorescence spectrum, zeta potential measurements and laser scanning confocal microscope(LSCM). The experiment results con¯rmed that the obtained hybrid nanostructures providedexcellent photostability, biocompatibility and active surface for further biological functionali-zation. The novel composite structures may have great potential application in cell multicolorlabeling and imaging instead of traditional °uorescent dyes.
Zhiqiang Lai,YAN-JIE GUO,Peihui Yang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2016 NANO Vol.11 No.12
As a IV–VI semiconductor, GeS is winning wide attention for its excellent properties. However, few examples of GeS nanostructures, especially those with photoluminescence (PL) properties, have been reported. After the optimization of reaction conditions, including time and temperature, the GeS nanowires with PL properties are synthesized via a green, facile hydrothermal route without using any toxic reagent. These materials are characterized by transmission and scanning electron microscopy (TEM and SEM), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), etc. With the average diameter of ~200 nm and the length ranging from 1–25 µm, the resulting GeS nanowires have relatively smooth surface and round top, and are oriented along [100] facet. The growth mechanism of GeS nanowires is investigated, and the understanding of their growth mechanism could provide helpful guidance for designing experimental conditions rationally to synthesize nanowires. Due to their special nanostructure, these nanowires possess very good fluorescent properties, which indicates that these nanowires have potential to apply in future optical nanodevices.