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      • KCI등재후보

        INTEGRATING NANOSCALE ZERO-VALENT IRON AND TITANIUM DIOXIDE FOR NUTRIENT REMOVAL IN STORMWATER SYSTEMS

        NI-BIN CHANG,FAHIM HOSSAIN,LEI ZHAI,KUEN-SONG LIN,MARTY WANIELISTA 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2008 NANO Vol.3 No.4

        Nutrients, such as nitrate, nitrite, and phosphorus, are common contaminants in many aquatic systems in the United States. Ammonia and nitrate are both regulated by the drinking water standards in the US primarily because excess levels of nitrate might cause methemoglobinemia. Phosphorus might become sources of the eutrophication problems associated with toxic algae in the freshwater bodies. Toxic algal blooms can cause severe acute and chronic public health problems. Chemical reduction of nitrate by using zero-valent iron started as early as 1964, and considerable research reports relating to this technology to nanomaterial were extensively reported in 1990s making the use of nanoscale zero-valent iron (NZVI) particles for nitrate removal become one of the most popular technologies in this field. The purpose of the present study was to examine the potential of integrating green sorption media, such as sawdust, limestone, tire crumb, and sand/silt, with two types of nanoparticles, including NZVI and Titanium Dioxide (TiO₂), for nitrate removal in an engineering process. The study consists of running packed bed column tests followed by the addition of NZVI and TiO₂ to improve nitrate and phosphorus removal efficiency. Preliminary results in this paper show that the potential and advanced study may support the creation of design criteria of stormwater and groundwater treatment systems for water reuse in the future.

      • KCI등재후보

        SYNTHESIS AND CHARACTERIZATION OF TITANIA NANOTUBES FOR DYE WASTEWATER TREATMENT

        KUEN-SONG LIN,CHAO-CHUN LO,NI-BIN CHANG 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2008 NANO Vol.3 No.4

        This paper starts with the preparation of anatase titania nanotube (TN) in large quantities by hydrothermal routes with different calcination temperatures, and then delves into a thorough investigation for the characterization of fine structures or formation mechanism of TN. Experimentally, anatase TiO2 nanoparticle was used as a precursor for TN synthesis. The results showed that the length and diameter of TN range are 50–100 nm and 10–15 nm, respectively. The XRD patterns and BET isotherms indicated that TN owns anatase-typed structures with a surface area of 292m2/g. By extended X-ray absorption fine structure (EXAFS) spectra, the valency and framework of TN are Ti(IV) with octahedral structures. The EXAFS data also revealed that TN has a first shell of Ti–O bonding with bond distances of 1.95 Å and coordination numbers were 2. The results revealed that the TiO2 anatase nanoparticles can be solved into layer under strong alkaline. The layer of TN further curling itself to reduce the energetics was postulated and found. For calcination temperature larger than 400°C, the microstructure of TN might transform from nanotube into nanoparticles accompanying with the sharp increase for the nanoparticle crystalline phase. With the understanding of pore structure variation on the basic dye (Basic Green 5 (BG5)), the adsorption ability, mechanisms, and kinetics of (Basic Green 5 (BG5)) dye onto TN were examined as well.

      • KCI등재

        Highly Uniform Core/Shell Structured CoFe2O4/MIL-100(Fe) Nanofibers for Efficient Visible Light Photocatalysis

        Jun Liu,Meng Sun,Meng-Jie Chang,Si-Meng Fan,Qian Hui,Fu-Rong Ni,Bin Yuan 한국섬유공학회 2021 Fibers and polymers Vol.22 No.2

        Novel CoFe2O4/MIL-100(Fe) (CFO/MIL-100(Fe)) core/shell nanofibers were prepared by successive ionic layeradsorption and reaction (SILAR) assembly of MIL-100(Fe) on electrospun CoFe2O4 nanofibers. The MIL-100(Fe) shellswere constructed on the dispersed CoFe2O4 fiber surface with high uniformity, homogeneous thickness and high stability. Due to the inherent porosity of MIL-100(Fe), a higher specific surface area of 225.77 m2/g is achieved for the CFO/MIL-100(Fe)-10 sample. The formed CFO/MIL-100(Fe) catalysts exhibit high catalytic activity towards degradation of rhodamineB (RhB) under visible light irradiation. The photocatalytic activity remains above 77 % within 60 min illumination after fourcycles. Due to the simple synthetic method, highly uniform structure, strong magnetic recoverable, as well as goodphotocatalytic performance, the obtained CFO/MIL-100(Fe) core/shell nanofibers could be promising photocatalysts forpractical application.

      • KCI등재

        Novel Phage Display-Derived H5N1-Specific scFvs with Potential Use in Rapid Avian Flu Diagnosis

        ( Jie Wu ),( Xian Qiao Zeng ),( Hong Bin Zhang ),( Han Zhong Ni ),( Lei Pei ),( Li Rong Zou ),( Li Jun Liang ),( Xin Zhang ),( Jin Yan Lin ),( Chang Wen Ke ) 한국미생물 · 생명공학회 2014 Journal of microbiology and biotechnology Vol.24 No.5

        The highly pathogenic avian influenza A (HPAI) viruses of the H5N1 subtype infect poultry and have also been spreading to humans. Although new antiviral drugs and vaccinations can be effective, rapid detection would be more efficient to control the outbreak of infections. In this study, a phage-display library was applied to select antibody fragments for HPAI strain A/Hubei/1/2010. As a result, three clones were selected and sequenced. A hemagglutinin inhibition assay of the three scFvs revealed that none exhibited hemagglutination inhibition activity towards the H5N1 virus, yet they showed a higher binding affinity for several HPAI H5N1 strains compared with other influenza viruses. An ELISA confirmed that the HA protein was the target of the scFvs, and the results of a protein structure simulation showed that all the selected scFvs bound to the HA2 subunit of the HA protein. In conclusion, the three selected scFVs could be useful for developing a specific detection tool for the surveillance of HPAI epidemic strains.

      • KCI등재후보

        DECONTAMINATION OF NITRATES AND NITRITES IN WASTEWATER BY ZERO-VALENT IRON NANOPARTICLES

        KUEN-SONG LIN,TIEN-DENG CHUANG,NI-BIN CHANG 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2008 NANO Vol.3 No.4

        The chemical reduction of nitrate or nitrite species by zero-valent iron nanoparticle (ZVIN) in aqueous solution and related reaction kinetics or mechanisms using fine structure characterization were investigated. Experimentally, ZVIN of this study was prepared by borohydride reduction method at room temperature. The morphology of as-synthesized ZVIN shows that the nearly ball and ultrafine particles ranged of 20–50 nm were observed with FE-SEM analysis. The kinetic model of nitrites or nitrates reductive reaction by ZVIN is proposed as a pseudo-first-order kinetic equation. The nitrite and nitrate removal efficiencies using ZVIN were found 65–83% and 51–68%, respectively, based on three different initial concentrations. By using XRD patterns, the quantitative relationship between nitrite and Fe(III) or Fe(II) becomes similar to the one between nitrate and Fe(III) in the ZVIN study. The possible reason is linked with a faster nitrite reduction by ZVIN. In fact,the occurrence of the relative faster nitrite reductive reaction suggested that the passivation of the ZVIN have a significant contribution to iron corrosion. The XANES spectra show that the nitrites or nitrates reduce to N₂ while oxidizing the ZVIN to Fe₂O₃ or Fe₃O₄ electrochemically. It is also very clear that decontamination of nitrate or nitrite species in groundwater via the in-situ remediation with a ZVIN permeable reactive barrier would be environmentally attractive.

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