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Corrosion Behavior Optimization by Nanocoating Layer for Low Carbon Steel in Acid and Salt Media
( Ahmed S. Abbas ),( Bahaa Sami Mahdi ),( Haider H. Abbas ),( F. F. Sayyid ),( A. M. Mustafa ),( Iman Adnan Annon ),( Yasir Muhi Abdulsahib ),( A. M. Resen ),( M. M. Hanoon ),( Nareen Hafidh Obaeed ) 한국부식방식학회 2023 Corrosion Science and Technology Vol.22 No.1
In this paper, a SiC nano electroless nickel plating layer with excellent corrosion resistance was fabricated using the Taguchi method. The electroless plated low carbon steel was subjected to tests to examine the influence of corrosive media, microhardness, and corrosion rate on the corrosion resistance of this alloy. Three different corrosive media (HCl, Na<sub>2</sub>SO<sub>4</sub>, and NaCl) at various temperatures (80, 90, and 100 ℃) were used, and at three different times (40, 80, and 120 min.) with a speed of stirring equal to 500 rpm. The results of microhardness were found from 134.276 HV to 278.578 HV at various conditions, while the corrosion rate results were obtained from 0.89643 mpy to 7.12571 mpy at different circumstances. Corrosion, and mechanical characteristics were explained using Taguchi design. Taguchi technique was used to account for all possible combinations of elements in order to conduct a complete study. Models that link the response and procedure parameters were developed using the results of these tests, and the analysis of variance was utilized to validate these models (ANOVA). For maximum efficiency, a function called “desirability” was applied to all responses at once.
Ahmed A. Alamiery,Firas F. Sayyid,Ali M. Mustafa,Mahdi M. Hanoon,Lina M. Shaker 한국부식방식학회 2022 Corrosion Science and Technology Vol.21 No.2
Schiff base quinazoline derivative viz., 3-((2-hydroxy-3-methoxybenzylidene)amino)-2-methylquinazolin-4(3H)-one (SB-Q), was synthesized in this study. Its corrosion protection impact on mild steel (MS) in 1 Mhydrochloric acid solution was examined by performing weight loss measurements. The protective efficacyof SB-Q on MS in 1 M HCl was investigated based on its concentrations, immersion period, and immersion temperature. SB-Q was found to be an efficient inhibitor for the corrosion of MS. Its inhibitionefficiency was improved by increasing the concentration of SB-Q to an optimal concentration of 500 ppm. Its inhibition efficacy was 96.3% at 303K. Experimental findings revealed that its inhibition efficiency was increased with increasing immersion time, but decreased with an increase in temperature. The adsorption of SB-Q molecules was followed the Langmuir adsorption isotherm model. The adsorption of the examined inhibitor molecules on the surface of mild steel was studied by density functional theory (DFT). DFT investigation confirmed weight loss findings.
A. A. Al-Amiery,Firas F. Sayyid,Ali M. Mustafa,Slafa I. Ibrahim,Mustafa K. Mohsin,Mahdi M. Hanoon,Mohammed H. H. Al-Kaabi,A. A. H. Kadhum,Wan Nor Roslam Wan Isahak 한국부식방식학회 2023 Corrosion Science and Technology Vol.22 No.2
Due to continuous promotion of green alternatives to toxic petrochemicals by government policies,research efforts towards the development of green corrosion inhibitors have intensified recently. The objectiveof the current work was to develop novel green and sustainable corrosion inhibitors derived from 4-aminoantipyrine to effectively prevent corrosion of mild steel in corrosive environments. Gravimetricmethods were used to investigate corrosion inhibition of 4-((furan-2-ylmethylene)amino)antipyrine (FAP)and 4-((pyridin-2-ylmethylene)amino)antipyrine (PAP) for mild steel in 1 M HCl. FAP and PAP were subjectedto quantum chemical calculations using density functional theory (DFT). DFT was used to determinethe mechanism of mild steel corrosion inhibition using inhibitors tested in HCl. Results demonstratedthat these tested inhibitors could effectively inhibit mild steel corrosion in 1.0 M HCl. At 0.0005 M, theseinhibitors’ efficiencies for FAP and PAP were 93.3% and 96.5%, respectively. The Langmuir adsorptionisotherm was obeyed by these inhibitors on the mild steel surface. Values of adsorption free energies,, revealed that FAP followed chemical and physical adsorptions.