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        Preparation of light-transmissive conductive film by free arc dispersed carbon nanotubes and thermos compression bonding

        Li Shaolong,Qingdao University of Science and Technology,Qingdao University of Science and Technology,Qingdao University of Science and Technology,Liu Xingyang,He Yan,Zhang Chuanqi,Wang Jinyu,Fu Jinfe 한국탄소학회 2020 Carbon Letters Vol.30 No.6

        To investigate the efect of gas dispersing carbon nanotubes (CNTs) and hot pressing method on the transparency and the conductivity of thin flms, the free arc was used to disperse the CNTs in a high dispersion rate, and the dispersed CNTs were rapidly pressed into the surface of the PET flm by hot pressing to obtain electrical conductivity. The relationship between the light transmission and sheet resistance of the flm was studied by changing the deposition time and the presence or absence of electrostatic adsorption. It was found that the CNTs modifed flm still retains good electrical conductivity (sheet resist�ance up to 6×104 Ω, light transmittance 69%) through the cleaning of surfactants and ultrasonic waves, which proves that hot pressing is a simple physical method to achieve efective combination of CNTs and flms.

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        Iron-loaded carbon derived from separated microplastics for heterogeneous Fenton degradation of tetracycline hydrochloride

        Liu Hongwen,Li Xingyang,Li Guosheng,Yasser Vasseghian,Wang Chongqing 한국화학공학회 2023 Korean Journal of Chemical Engineering Vol.40 No.12

        Microplastics are gaining growing research interest due to their significant potential threats to ecosystems and public health. Physical techniques have been proposed as a promising strategy for removing microplastics from the environment. This work innovatively proposes a process of microplastic removal by froth flotation and subsequent carbonization for synthesis of heterogeneous Fenton catalyst. The feasibility of separating different microplastics from water was verified by froth flotation, and iron-loaded carbon derived from separated microplastics was fabricated as catalyst. Carbon material was obtained by carbonization of microplastics, and iron loading was conducted to improve catalytic ability. The catalyst of iron-loaded iron was characterized by scanning electron microscopy and energy-dispersive X-ray spectroscopy. The degradation of tetracycline hydrochloride in the heterogeneous Fenton system was evaluated by single factor experiment and kinetic analysis. The catalytic performance was mainly influenced by H2O2 concentration, solution pH, and co-existing ions. Under the conditions of catalyst 20 mg/L, H2O2 concentration 0.99 mmol/L, initial tetracycline hydrochloride concentration 20 mg/L, pH 4.0, and temperature 25 °C, the removal rate of tetracycline hydrochloride within 15 min reached 81.6%, and the rate constant was 0.138min−1. The catalytic mechanism dominated by hydroxyl radical was verified for the degradation of tetracycline hydrochloride. This work offers insights into the management of microplastics and sustainable treatment of antibiotic wastewater.

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        The conditional risk probability-based seawall height design method

        Xing Yang,Xiaodong Hu,Zhiqing Li 대한조선학회 2015 International Journal of Naval Architecture and Oc Vol.7 No.6

        The determination of the required seawall height is usually based on the combination of wind speed (or wave height) and still water level according to a specified return period, e.g., 50-year return period wind speed and 50- year return period still water level. In reality, the two variables are be partially correlated. This may be lead to overdesign (costs) of seawall structures. The above-mentioned return period for the design of a seawall depends on economy, society and natural environment in the region. This means a specified risk level of overtopping or damage of a seawall structure is usually allowed. The aim of this paper is to present a conditional risk probability-based seawall height design method which incorporates the correlation of the two variables. For purposes of demonstration, the wind speeds and water levels collected from Jiangsu of China are analyzed. The results show this method can improve seawall height design accuracy.

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