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        Tuning of the Curie Temperature in La1-xSrxMn1-yTiyO₃

        N. X. Phuc,N. T. Hieu,N. T. H. Le,D. H. Manh,N. A. Tuan,L. V. Hong,L. T. C. Tuong 한국물리학회 2008 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.52 No.5

        Magnetic nanoparticles of La₁-xSrxMn₁-yTiyO₃ were prepared by using a sol-gel method, followed by annealing at various elevated temperatures. We found that the Curie temperature of the manganite nanoparticles could easily be tuned (from TC ~ 90 ℃ down to ~20 ℃) by substitution of nonmagnetic Ti⁴+ ions (from y = 0 to 7 %) for Mn. A comparison showed that the titanium substitution approach had advantages such as the phase transition being sharper and the magnetization remaining higher than in the case of the earlier known way of TC reduction by decreasing the Sr content from the optimal value of x = 0.3. The new features seem to make La1..xSrxMn₁..yTiyO₃ nanoparticles promising for hyperthermia application. Magnetic nanoparticles of La₁-xSrxMn₁-yTiyO₃ were prepared by using a sol-gel method, followed by annealing at various elevated temperatures. We found that the Curie temperature of the manganite nanoparticles could easily be tuned (from TC ~ 90 ℃ down to ~20 ℃) by substitution of nonmagnetic Ti⁴+ ions (from y = 0 to 7 %) for Mn. A comparison showed that the titanium substitution approach had advantages such as the phase transition being sharper and the magnetization remaining higher than in the case of the earlier known way of TC reduction by decreasing the Sr content from the optimal value of x = 0.3. The new features seem to make La1..xSrxMn₁..yTiyO₃ nanoparticles promising for hyperthermia application.

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