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Satoshi Wada,H. Kakemoto,K Yokoh,T Tsurumi,T Muraishi 한국물리학회 2007 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.51 No.2I
The phase transition behaviors of [111]-oriented barium titanate (BaTiO3) crystals were investigated as functions of temperature, uniaxial stress, and electric field. For the phase transition caused by temperature, with decreasing temperature above Tc, the paraelectric phase changed to an intermediate phase with a superparaelectric state and finally changed to a ferroelectric phase with randomly oriented spontaneous polarizations. Moreover, the phase transition caused by the uniaxial stress field above Tc was found to be almost similar to the one caused by temperature. On the other hand, for the phase transition caused by an electric field above Tc, with increasing electric field, the paraelectric phase changed to an intermediate phase and finally to a ferroelectric phase with an oriented polar direction. These results suggest that above Tc, a combination of uniaxial stress with an electric field may be effective as a poling treatment for BaTiO3 crystals. Thus, in this study, a new poling method for the BaTiO3 crystals by using control of the temperature, the uniaxial stress, and the electric field is proposed.t