http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Jinghong Zhang,Dong Fu,Shu Qin Wang,Runlong Hao,Yixiao Xie 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.80 No.-
To cooperatively oxidize sulfite and reduce Cr(VI), this paper proposed a visible-light drivenphotocatalytic method, with using the photocatalysts of transition metals (Cu, Fe and Zn) dopedTiO2. The photocatalysts were characterized by means of XRD, BET, SEM and UV–vis. 0.5Cu-TiO2 exhibitedthe best performance, and the existing forms of Ti and Cu were Ti4+/Cu+ and/or Cu-O-Ti. Cu-dopingintroduced an energy level of Cu 3d which was useful in decreasing the band gap and increasing thevisible light utilization. Cu-doping also made the TiO2 grains well dispersed, increased the amount ofhydroxyl group, decreased the grain size and increased the specific surface area, which facilitated theadsorption process. Hydrothermal method (8 h and 180 C) favored the formation of anatase crystal. FT-IRresults revealed that most of produced Cr(III) and sulfate were adsorbed onto the catalyst. Kinetics resultssuggested that the rate constant for Cr(VI) removal was 5.05 10 3 min 1. The photo-produced electrons(e ) and holes (h+) contributed to the reduction of Cr(VI) and oxidation of sulfite, respectively; thecontinual consumption of e and h+ enhanced the separation of the h+-e pairs.
Jinghong Zhou,Long Zhao,Hong Chen,Mingguang Zhang,Zhijun Sui,Xinggui Zhou 한국화학공학회 2010 Korean Journal of Chemical Engineering Vol.27 No.5
Carbon nanofiber (CNFs) supported Ru catalysts for sorbitol hydrogenolysis to ethylene glycol and propylene glycol were prepared by incipient wetness impregnation, calcination and reduction. The effect of calcination on catalyst properties was investigated using thermal gravimetry analysis, temperature-programmed reduction, X-ray diffraction,X-ray photoelectron spectroscopy, transmission electron microscopy and N2 physisorption. The results indicated that calcination introduced a great amount of surface oxygen-containing groups (SOCGs) onto CNF surface and induced the phase transformation of Ru species, but slightly changed the texture of Ru/CNFs. The catalytic performance in sorbitol hydrogenolysis showed that Ru/CNFs catalyst calcined at 240 oC presented the highest glycol selectivities and reasonable glycol yields. It was believed that the inhibition and confinement effect of SOCGs around Ru particles as well as the high dispersion of Ru particles was the key factor for the catalytic activity.