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Guoyong Wang,Yanyan Zhu,Yunhui Zhai,Wanxu Wang,Zhiping Du,Jieqiong Qin 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.47 No.-
A simple process to synthesize polyglycerol modified polysiloxane surfactants has been carried outapplying a “grafting-to” approach. After formation of allyl polyglycerol ether (APGE) from diglycerol(DGY) and allyl glycidyl ether (AGE), polysiloxane modified by designed number of polyglycerol groups(PHMS-APGE) were obtained by connecting the APGE structure to different Si H functionalizedpolyhydromethyl siloxane (PHMS). The synthesized APGE-PHMS were characterized by IR and 1H NMR. Solubility measurements showed that the solubility of the as-prepared polymers increased in polarsolvents with the increasing of the amount of hydrophilic APGE groups. Furthermore, the surface activity,surface adsorption, aggregation and spreading behaviors of APGE-PHMS were investigated utilizingsurface tension measurements, dynamic light scattering (DLS), transmission electron microscopy (TEM)and contact angle measurements. The results showed that critical aggregation concentration (CAC) andthe time needed to reach adsorption equilibrium on water surface decrease systematically with theincrease in the number of APGE groups. These polymers in aqueous solutions could aggregate to formspherical assemblies. Moreover, the spreading behavior of these polymers on low energy surface wasfound to be influenced by the number of hydrophilic APGE groups.