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The Oxidation of Hydrazobenzene by Oxygen Catalysed by Co (3MeOsalen) in Methanol
Homer Roger B.,Cannon Roderick D.,Kim Stephen S.B. Korean Chemical Society 1985 Bulletin of the Korean Chemical Society Vol.6 No.2
The oxidation of hydrazobenzene by oxygen in methanol solution is catalysed by Co(3MeOsalen) which is a synthetic oxygen carrier. The products are trans-azobenzene and water. The rate of the reaction has been studied spectrophotometrically and the rate law established. A mechanism involving a ternary complex of catalyst, hydrazobenzene and oxygen has been proposed.