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Photoluminescence properties of NaGd(WO_4)_2:Eu^3+ nanocrystalline prepared by hydrothermal method
Jinsheng Liao,Hangying You,Bao Qiu,He-Rui Wen,Ruijin Hong,Weixiong You,Zhipeng Xie 한국물리학회 2011 Current Applied Physics Vol.11 No.3
NaGd(WO_4)_2:Eu^3+ (hereafter NGW:Eu) red-phosphors were synthesized via a facile hydrothermal method at different pH value. X-ray power diffraction (XRD), transmission electron microscope (TEM),energy dispersive X-ray spectra (EDS), photoluminescence excitation and emission spectra and decay curve were used to characterize the NGW:Eu phosphors. It was found that the pH value has a crucial effect on synthesis of the scheelite structure NGW:Eu. The intense red emission is obtained by exciting into the 5^L_6 state with 395 nm, which corresponds to the popular emission line from near-UV LED chips. The values of Ω2,4 experimental intensity parameters (14.9 × 10^-20 and 5.6 × 10^-20 cm^2) are determined. The high emission quantum efficiency and suitable color coordination of the NGW:Eu phosphor suggest the material could be a promising red phosphor for generating white light in phosphor-converted white light emitting diodes (WLEDs).