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Han Gyeol Kim,Joonho Lee,Guy Makov 대한금속·재료학회 2020 METALS AND MATERIALS International Vol.26 No.5
Bi–Sn alloy phase diagram under pressure was re-calculated using the CALculation of PHAse Diagrams method by applyingnew density data. Theoretically, alloy phase diagram under pressure can be calculated with bulk thermodynamic databaseand thermophysical property data such as density and sonic velocity. In the recent study by Emuna et al. (J Alloys Compd687:360–369, 2016), thermodynamic parameters were determined from literature values with additional modification tofit experimental data of phase boundaries. In this study, density of liquid Bi–Sn alloys was re-evaluated with an advanceddensity measurement technique: the constrained drop method. By applying the new density data, the Bi–Sn phase diagramunder pressure could be calculated successfully without any modification of thermodynamic parameters.