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Synthesis and characterization of phenol-formaldehyde resin using enzymatic hydrolysis lignin
Wei Qiao,Shujun Li,Guowan Guo,Shiyan Han,Shixue Ren,Yanli Ma 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.21 No.1
Enzymatic hydrolysis lignin (EHL) was utilized to partially replace phenol for preparing phenolformaldehyde(PF) resin. The influence of lignin substitution rate on the properties of the lignin-modifiedphenol-formaldehyde (LPF) resin was investigated. Lignin substitution of 60 wt% did not deteriorate theadhesive strength of PF resin. FTIR analysis of the resins revealed that the incorporation of EHL made nobig difference in chemical structure, but led to a deteriorated thermal resistance. The comparisonbetween LPF and bio-ethanol production residue-modified phenol-formaldehyde (RPF) resins elucidatedthat the purification processwas beneficial for its higher substitution application and better performanceof adhesive.