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Solid-State Scrolls from Hierarchical Self-Assembly of T-Shaped Rod–Coil Molecules
Hong, Dong-Je,Lee, Eunji,Jeong, Haemi,Lee, Jeong-kyu,Zin, Wang-Cheol,Nguyen, Trung Dac,Glotzer, Sharon C.,Lee, Myongsoo WILEY-VCH Verlag 2009 Angewandte Chemie Vol.48 No.9
<P>On a roll: Attachment of flexible coils to the middle of a rigid rod generates T-shaped rod–coil molecules that self-assemble into layers that roll up to form filled cylindrical and hollow tubular scrolls, depending on the coil length, in the solid state (see picture); the rods are arranged parallel to the layer plane. <img src='wiley_img_2010/14337851-2009-48-9-ANIE200804307-content.gif' alt='wiley_img_2010/14337851-2009-48-9-ANIE200804307-content'> </P> <B>Graphic Abstract</B> <P>On a roll: Attachment of flexible coils to the middle of a rigid rod generates T-shaped rod–coil molecules that self-assemble into layers that roll up to form filled cylindrical and hollow tubular scrolls, depending on the coil length, in the solid state (see picture); the rods are arranged parallel to the layer plane. <img src='wiley_img_2010/14337851-2009-48-9-ANIE200804307-content.gif' alt='wiley_img_2010/14337851-2009-48-9-ANIE200804307-content'> </P>