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Mingxia Yu,Huosheng Li,Keke Li,Yuting Li,Fengli Liu,Gaosheng Zhang,Tangfu Xiao,Ping Zhang,Hongguo Zhang,Jianyou Long 한국섬유공학회 2022 Fibers and polymers Vol.23 No.2
Decolorization and organic degradation of wastewater containing multiple dyes are still challenging inwastewater treatment. Magnetic biochar coupled with advanced oxidation is a potential solution to this issue. In this study,a series of magnetite-based biochar composites (Fe3O4@C) was prepared and compared for the removal of mixed dyes,including methyl orange (MO), rhodamine B (RhB), methylene blue (MB), and an organic macromolecule, humic acid(HA). The pyrolysis of watermelon rinds followed by precipitation of Fe3O4 onto the biochar was selected as the optimummethod to prepare an adsorbent and catalyst to couple binary oxidants (hypochlorite and persulfate) for color and totalorganic carbon removal. Persulfate was prone to degrade HA and MB, while hypochlorite was inclined to oxidize MO andRhB. Fe3O4@C exhibited better dye removal performance in coupling with binary oxidants than with a single oxidant. Formixed dye solutions with an initial concentration of 50 mg/l for each dye, the highest TOC (57.24±3.17 %) and the colorremoval efficiencies (94.13±1.68 %) for the mixed dye solution were achieved at a sorbent dosage of 1 g/l and an oxidantdosage of 5 mmol/l for both hypochlorite and persulfate. Multiple free radicals, including hydroxyl radicals, sulfateradicals, and hypochlorite-induced radicals, play critical roles in the degradation of mixed dyes and color removal. Theregeneratibility and reutilization of the magnetic Fe3O4@C composite were effective and stable. The results obtained inthis study show that the combined Fe3O4@C and binary oxidants technique is promising for the treatment of multi-dyewastewater.