http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Franz E. Lopez-Suarez,Daniel M. Riveros-Riveros,Yolanda Cesteros,Pilar Salagre 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.94 No.-
This study evaluates the techno-economic feasibility to produce tert-butyl ethers of glycerol in Colombiausing glycerol obtained from biodiesel production. The major drawback of this process is related to thehigh costs associated to the isobutylene reagent used for this reaction. Three possible scenarios, usingisobutylene: glycerol molar ratios of 2:1 and 4:1, have been evaluated by simulation and technoeconomicalassessment using pure isobutylene, C4 fraction and a mixture of C4 and isobutylene as well asa refining stage for crude glycerol. The desired product, a mixture of di- and tri- ethers of glycerol (h-GTBE) was obtained in high amounts for the three scenarios (92–99 wt.%) and a direct relation betweenproduction cost and raw material cost was established. The prices for h-GTBE were higher than theproposed selling prices; however, the formation of byproduct (C4 fraction) can make the processcompetitive. h-GTBE production did not have a competitive price for any scenario at high isobutylene:glycerol molar ratio. The production price was lowered by around 20% for all scenarios when crudeglycerol was considered. Finally, competitive price of h-GTBE (0.96 $/kg) and NPV positive was obtainedusing a mixture of C4 and isobutylene and crude glycerol.