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Zhang, Yakun,Li, Jianling,Kang, Feiyu,Wang, Xindong,Ye, Feng,Yang, Jun Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.6
The polymer of (2,2-dimethyl-1,3-propanediaminebis(salicylideneaminato))-nickel(II), Ni(saldMp), was deposited on multi-walled carbon nanotubes (MWCNTs) substrate by the route of potential linear sweep. The nano structures of poly[Ni(saldMp)] have been obtained by adjusting the monomer concentration of 0.1, 0.2, 0.5, 1.0 and 1.5 mmol $L^{-1}$. The poly[Ni(saldMp)] prepared in acetonitrile solution with monomer concentration of 1.0 mmol $L^{-1}$ shows the fastest growth rate. The effects of potential window on charge-discharge efficiency and electrodeposition scan number on capacitance performance were discussed. Poly[Ni(saldMp)] prepared with less electrodeposition scans exhibits higher capacitance, but this goes against the improvement of the whole electrode capacitance. Sample with 8 deposition scans is the best compromise with the geometric specific capacitance 3.53 times as high as that of pure MWCNTs, and 1.24 times for the gravimetric specific capacitance under the test potential window 0.0-1.0 V.
Yakun Zhang,Jianling Li,Feiyu Kang,Xindong Wang,Feng Ye,Jun Yang 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.6
The polymer of (2,2-dimethyl-1,3-propanediaminebis(salicylideneaminato))-nickel(II), Ni(saldMp), was deposited on multi-walled carbon nanotubes (MWCNTs) substrate by the route of potential linear sweep. The nano structures of poly[Ni(saldMp)] have been obtained by adjusting the monomer concentration of 0.1, 0.2, 0.5, 1.0 and 1.5 mmol L−1. The poly[Ni(saldMp)] prepared in acetonitrile solution with monomer concentration of 1.0 mmol L−1 shows the fastest growth rate. The effects of potential window on charge-discharge efficiency and electrodeposition scan number on capacitance performance were discussed. Poly[Ni(saldMp)] prepared with less electrodeposition scans exhibits higher capacitance, but this goes against the improvement of the whole electrode capacitance. Sample with 8 deposition scans is the best compromise with the geometric specific capacitance 3.53 times as high as that of pure MWCNTs, and 1.24 times for the gravimetric specific capacitance under the test potential window 0.0-1.0 V.
Zhang, Biao,Yu, Yang,Huang, Zhendong,He, Yan-Bing,Jang, Donghyuk,Yoon, Won-Sub,Mai, Yiu-Wing,Kang, Feiyu,Kim, Jang-Kyo The Royal Society of Chemistry 2012 ENERGY AND ENVIRONMENTAL SCIENCE Vol.5 No.12
<P>SnO<SUB><I>x</I></SUB>–carbon nanofiber (CNF) composites are synthesized using the electrospinning technique for use as freestanding electrodes in Li-ion batteries. The electrodes made from the composites carbonized at 750 °C (SnO<SUB><I>x</I></SUB>–CNF-750) with 14.5 wt% SnO<SUB><I>x</I></SUB> deliver a remarkable capacity of 674 mA h g<SUP>−1</SUP> after 100 cycles when discharged at 0.5 A g<SUP>−1</SUP>. This result is considered the highest among those reported in the literature for anodes made from similar electrospun carbon fibers containing SnO<SUB><I>x</I></SUB> nanoparticles. An increase in carbonization temperature to 950 °C (SnO<SUB><I>x</I></SUB>–CNF-950) results in a significant reduction of the particle content in the fiber due to aggregation of Sn to form nanoparticles external to the fibers, with concomitant degradation of capacities. The presence of amorphous SnO<SUB><I>x</I></SUB> particles at the atomic scale embedded in the conductive CNFs is thought to be responsible for the exceptional electrochemical performance of the SnO<SUB><I>x</I></SUB>–CNF-750 electrodes. These ultrafine particles facilitate the reaction Sn + <I>x</I>Li<SUB>2</SUB>O → SnO<SUB><I>x</I></SUB> + 2<I>x</I>Li<SUP>+</SUP> + 2<I>x</I>e<SUP>−</SUP>, making it highly reversible, which is confirmed by the growing peak currents with increasing scan rate indicated by cyclic voltammetry, and the absence of Sn–Sn bonds in the particles revealed by the extended X-ray absorption fine structure spectroscopy (EXAFS). Both the SnO<SUB><I>x</I></SUB> particle size and content in the fiber play important roles in controlling the rate and cyclic performance of the SnO<SUB><I>x</I></SUB>–CNF composite electrodes.</P> <P>Graphic Abstract</P><P>This paper presents novel SnO<SUB><I>x</I></SUB>–carbon nanofiber composites with embedded ultrafine SnO<SUB><I>x</I></SUB> particles. The composites deliver remarkable power/energy densities as well as excellent cyclic performance due to their high reversibility and stability. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c2ee23145j'> </P>