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Modeling and simulation of drying characteristics on flexible filamentous particles in rotary dryers
Conghui Gu,Chao Zhang,Xin Zhang,Naihong Ding,Bin Li,Zhulin Yuan 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.1
Experiments were conducted to demonstrate the effects of the drum wall temperature on the heat and mass transfer in rotary dryers. The drying characteristics of flexible filamentous particles in rotary dryers were further explored. In addition, the inlet and outlet temperatures and moisture contents of granular particles were measured. As a result, the good agreement between the simulations and experiments verified the rationale and feasibility of the numerical method. Therefore, the approach was adopted to evaluate the temperature and moisture content of wet granular particles in a rotary dryer in different conditions, for instance, drum wall temperature and rotational speed. The results revealed that the higher drum wall temperature led to hotter particles with lower outlet moisture content. Conversely, the higher rotational speed resulted in cooler particles with higher outlet moisture content due to the decrease of residence time in the rotary dryer.
Yiting Xu,Jianjie Xie,Lingnan Chen,Conghui Yuan,Yinyin Pan,Ling Cheng,Weiang Luo,Birong Zeng,Lizong Dai 한국고분자학회 2013 Macromolecular Research Vol.21 No.12
A novel organic/inorganic hybrid amphiphilic random copolymer poly(methacrylate isobutyl POSS-co-N-isopropylacrylamide-co-oligo(ethylene glycol) methyl ether methacrylate-co-2-vinylpyridine), poly(MAPOSS-co-NIPAM-co-OEGMA-co-2VP), was synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization. The self-assembly behavior of random copolymers in aqueous solution was investigated by dynamic light scattering (DLS) as well as transmission electron microscopy (TEM). The results indicate the novel random copolymer in water could self-assemble into spherical aggregates and the self-aggregate size displays a remarkable dependence on pH. The stimuli-responsive characteristics of these assembles were tested by means of UV-vis spectra,DLS and TEM. There is a critic Zn2+ concentration over which the aggregates can be coordinated into well-define spherical aggregate clusters. The critic Zn2+ concentration can be tuned finely through adjusting solution concentration or 2VP amount. Results from UV-vis and DLS reveal that the copolymer solutions exhibit a sharp and intensive lower critical solution temperature (LCST). Some factors such as the solution concentration, molecular weight, pH and copolymer generation, which could affect the cloud point, were studied systematically. The essentially predetermined LCST can be achieved by altering the content of 2VP or pH. In addition, these novel hybrid aggregates can undergo an association/disassociation cycle with the heating and cooling of solution and the degree of reversibility shows a strong concentration dependence. As a novel organic-inorganic hybrid material which can respond to multiple external stimuli including temperature, pH, metal ions with sharp stimuli-responsive behaviors, it is potentially used for biomedicine, catalysis, diagnostics, bioseparations, biosensors and for fundamental investigation.
Yiting Xu,Jiamei Huang,Yuntong Li,Meijie Wang,Ying Cao,Conghui Yuan,Birong Zeng,Lizong Dai 한국고분자학회 2017 Macromolecular Research Vol.25 No.8
A novel zwitterionic hybrid amphiphilic copolymer containing polyhedral oligomericsilsesquioxane (POSS), and poly(methacrylate isobutyl POSS)-b-poly (3-dimethyl(methacryloyloxyethyl) ammonium propane sulfonaten-co-2-(diethylamino) ethyl methacrylate-co-styrene) (PMAiBuPOSS-b-P(DMAPS-co-DMAEMAco- St)), was prepared by the ring open reaction of 1, 3-propane sultone with tertiary amine on the precursor polymer. This hybrid copolymer could self-assemble into spherical micelle with a relatively narrow size distribution. The micelle size exhibited a great dependence on pH, as the size of the micelles was of evidently decreases with the increase of the pH value. Controllable release of pyrene from the micelles was investigated by fluorescent emission spectra. Micelles with more zwitterionic units would lead to less pyrene release and longer equilibrium time. The protein adsorption resistance of the micelles was tested by mixing them with fetal bovine serum. The antifouling ability was improved by increasing the number of zwitterionic units as well as decreasing the number of DMAEMA units. This novel hybrid amphiphilic random copolymer with the pH-responsive and anti-protein-fouling ability, can be potentially used for drug carriers for controlled release.