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      • Fluorescent Microarrays of <i>in Situ</i> Crystallized Perovskite Nanocomposites Fabricated for Patterned Applications by Using Inkjet Printing

        Liu, Yang,Li, Fushan,Qiu, Lichun,Yang, Kaiyu,Li, Qianqian,Zheng, Xin,Hu, Hailong,Guo, Tailiang,Wu, Chaoxing,Kim, Tae Whan American Chemical Society 2019 ACS NANO Vol.13 No.2

        <P>Perovskite materials have exhibited promising potential for universal applications including backlighting, color conversion, and anticounterfeiting labels fabricated using solution processes. However, owing to the tendency of those materials to have uncontrollable morphologies and to form large crystals, they cannot be utilized in discontinuous microminiaturization, which is crucial for practical optoelectronic applications. In this research, combining the effects of adding polyvinylpyrrolidone (PVP), precisely controlling the inkjet printing technique, and using a postprocessing procedure, we were able to fabricate <I>in situ</I> crystallized perovskite-PVP nanocomposite microarrays with perfect morphologies. The viscosity of the perovskite precursor increased with the addition of PVP, eliminating the outward capillary flow that induces the coffee-ring effect. In addition, because of the presence of metallic bonds with the C═O groups in PVP and the spatial confinement of such a polymer, we were able to fabricate regulated CsPbBr<SUB>3</SUB> nanocrystals capped with PVP and with a uniform size distribution. The as-printed patterns showed excellent homogeneity on a macroscale and high reproducibility on a microscale; furthermore, those patterns were invisible in the ambient environment, compatible with flexible substrates, and cost-efficient to produce, indicating that this technique holds promising potential for applications such as anticounterfeiting labels.</P> [FIG OMISSION]</BR>

      • Inkjet-Printed Photodetector Arrays Based on Hybrid Perovskite CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Microwires

        Liu, Yang,Li, Fushan,Perumal Veeramalai, Chandrasekar,Chen, Wei,Guo, Tailiang,Wu, Chaoxing,Kim, Tae Whan American Chemical Society 2017 ACS APPLIED MATERIALS & INTERFACES Vol.9 No.13

        <P>Hybrid perovskite CH3NH3PbI3 has attracted extensive research interests in optoelectronic devices in recent years. Herein an inkjet printing method has been employed to deposit a perovskite CH3NH3PbI3 layer. By choosing the proper solvent and controlling the crystal growth rate, hybrid perovskite CH3NH3PbI3 nanowires, microwires, a network, and islands were synthesized by means of inkjet printing. Electrode-gap-electrode lateral-structured photodetectors were fabricated with these different crystals, of which a hybrid perovskite microwire-based photodetector would balance the uniformity and low defects to obtain a switching ratio of 16000%, responsivity of 1.2 A/W, and normalized detectivity of 2.39 x 10(12) Jones at a light power density of 0.1 mW/cm(2). Furthermore, the hybrid perovskite microwire-based photodetector arrays were fabricated and applied in an imaging sensor, from which the clear mapping of the light source signal was successfully obtained. This work paves the way for the realization of low-cost, solution-processed, and high-performance hybrid perovskite-based photodetector arrays.</P>

      • Experimental research on free vibration of curved composite box-girders with corrugated steel webs

        Yunsheng Li,Qingnian Dai,Chaoxing Liu,Yanling Zhang 국제구조공학회 2021 Steel and Composite Structures, An International J Vol.41 No.1

        The curved composite box-girders (CBGs) with corrugated steel webs (CSWs) have been used widely in bridges due to their great advantages and the demand of the road alignment, but the curvature makes both the static and dynamic behaviors more complex. To research the free vibration performance of the curved CBGs with CSWs, 5 simply-supported test girders were designed with the span-to-radius ratio (λ=L/R), the number of the cells of the box section, and the number of the diaphragms as parameters. The natural frequencies and mode shapes were measured in the experiment. The experimental results were compared with the numerical results using ANSYS software, and a satisfying agreement was obtained. The parametric analysis shows that for the curved CBG with CSWs, the vertical mode shapes are combined flexural and torsion, and the contribution of the torsional effects to the mode shapes and frequencies improve with the increase of λ, which leads to a decrease in the vertical and lateral frequencies and increase in the torsional frequency. The corrugated angle of the steel web has little effect on the natural frequencies of the curved CBGs with CSWs. Increasing the thickness of the steel web and the number of the diaphragms can improve the torsional rigidity of the curved CBG with CSWs effectively; while the deck width has a great contribution on the lateral rigidity.

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