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- 저자 : Changlong Yin (검색결과 3 건)
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Changlong Yin,Yiyan Wang 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.4
Oxidic unsupported Ni-Mo-W catalysts were chosen to elucidate the effect of sulfidation conditions on the catalytic performance. The catalysts were sulfided in situ by using dimethyl sulfide as sulfiding agent. The relationships between the time needed for sulfidation and the sulfiding conditions were studied by GC-analysis method. Straight-run gas oil with high sulfur and nitrogen content was used to evaluate the hydrotreating performance. The oxidic catalyst precursors and sulfided catalysts were characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and X-ray photoelectron spectroscopy (XPS). With increasing sulfiding liquid hourly space velocity (LHSV) of the sulfiding agent, the reaction time necessary for the sulfidation decreased, while the activity of the catalyst increased significantly. The higher catalytic activity might be due to the MoS2/WS2 slabs with shorter length and higher stacking number, which might contribute to the catalyst with more active sites. Sulfiding at 330 oC took the longest sulfidation time, while the catalytic activity was also the highest after sulfiding at this temperature. Furthermore, within a certain range, the sulfidation pressure had no evident effect on the catalytic behavior or activity. The purpose of this work was to provide a basis for actual production and a reference for further research.
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Effect of naphthalene quinoline and H2S on DBT hydrodesulfurization over unsupported NiMoW catalyst
Changlong Yin,Haonan Zhang,Tongtong Wu,Zhuyan Wu,Kunpeng Li,Yan Kong,Chengwu Dong,Chenguang Liu 한국화학공학회 2019 Korean Journal of Chemical Engineering Vol.36 No.12
Unsupported catalysts have attracted much attention for high activity in comparison with the traditional supported catalyst. Meanwhile, the clear structure of unsupported catalysts is helpful for the recognition of active phase for conducting the industry production. The NiMoW unsupported catalyst was prepared by hydrothermal synthesis and characterized by BET, XRD and HRTEM. The effects of naphthalene, quinoline and H2S on the hydrodesulfurization reactivity of dibenzothiophene (DBT) were investigated in both a batch autoclave and a continuous 10 ml fixed bed micro-reactor over NiMoW and supported catalyst for comparison. The results showed that the hydrogenation reaction and the hydrogenolysis reaction occurred on different active sites. For supported catalyst, the inhibition was relatively weaker, and the inhibition of the hydrodesulfurization pathway was much higher than the direct desulfurization pathway. Although unsupported catalyst was very sensitive to quinoline and H2S in this experiment, the HDS ratio on the unsupported catalyst was maintained at a high level above 99.7%, which is attributed to the very high active site density of unsupported catalysts.
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중국 모바일 결제서비스의 발전과 사용동기 - 중국 모바일 결제서비스 알리페이, 위챗페이를 중심으로 -
윤창룡 ( Changlong Yin ),이새봄 ( Sae-bom Lee ),노인성 ( In-sung Roh ),서영호 ( Yung-ho Suh ) 한국품질경영학회 2017 품질경영학회지 Vol.45 No.1
Purpose: The purpose of this study is how Chinese users` personal traits affect the intention to use mobile payment. This research selects personal innovativeness and habit of cash payment as personal traits, and considers perceived risks and relative advantage as personal beliefs. In addition, the research divided perceived risks into three multi-faceted risks, which are privacy risk, financial risk and performance risk. Methods: The method of this study used questionnaire survey to collect 241 data on users` perception on mobile payment, and also used a structural equation modeling method. Results: The result of this paper shows that all hypotheses are statistically significant except 4 hypotheses. Conclusion: The result of this study found that personal innovativeness is negatively related with all 3 kinds of perceived risks as anticipated. And Chinese users` traditional habit of cash payment negatively affects intention to use mobile payment but is not statistically significant affecting three perceived risks. Among perceived risks, privacy risk is the most negatively influencing factor to relative advantage.
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