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        High-temperature-treated multiwall carbon nanotubes for hydrogen evolution reaction

        Nguyen, Tri Khoa,Bannov, Alexander G.,Popov, Maxim V.,Yun, Jong-Won,Nguyen, Anh Duc,Kim, Yong Soo Elsevier 2018 International journal of hydrogen energy Vol.43 No.13

        <P><B>Abstract</B></P> <P>We investigated the hydrogen evolution reaction (HER) properties of multi-wall carbon nanotubes (MWCNTs) treated at extremely high temperature (2600 °C). The heat treatment not only improves the crystallinity of the MWCNTs, but also reduces the carbon-oxygen (CO) bonding as it is replaced by the defect-carbon (<I>sp</I> <SUP>3</SUP> and CH) bonding. These modifications in the heat treated MWCNT structure lead to the increase of electrochemical charge transfer. The heat treatment of MWCNTs in the composite with Pt (MWCNT-Pt composite) further facilitates electrocatalysis. The MWCNTs-Pt composite shows strong enhancement in the HER performance with an onset of overpotential of −0.04 V vs reversible hydrogen electrode and a Tafel slope of 10.9 mV/decade. This performance is indeed better than that of Pt, which is the best working material for HER.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Heat treatment effects to reorder nanotube structures by connecting the broken crystals. </LI> <LI> CO bonding density is reduced and porosity properties are increased after heat treatment. </LI> <LI> Hydrogen evolution reaction (HER) performance is enhanced after heat treatment. </LI> <LI> Charge transfer resistance in HER is strongly decreased after heat treatment. </LI> <LI> Heat-treated MWCNT-Pt composite yields the excellent HER properties. </LI> </UL> </P>

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