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      • KCI등재

        Association of Serum Vitamin D Levels with Bacterial Load in Pulmonary Tuberculosis Patients

        ( B. Yuvaraj ),( M. G. Sridhar ),( D. N. B. ),( S. Vinod Kumar ),( T. Kadhiravan ) 대한결핵 및 호흡기학회 2016 Tuberculosis and Respiratory Diseases Vol.79 No.3

        Background: Vitamin D is known to have diverse effects on various systems in the body. There is evidence to suggest that a link exists between the serum vitamin D status and tuberculosis. The present study was designed to assess the alterations in serum 25-hydroxyvitamin D levels in newly diagnosed sputum acid fast bacilli (AFB) positive pulmonary tuberculosis patients and to study the association, if any, between serum vitamin D levels and different levels of sputum smear positivity. Methods: Serum 25-hydroxyvitamin D levels were estimated in 65 sputum AFB positive pulmonary tuberculosis patients and 65 age and gender-matched healthy controls. Results: The levels of serum 25 hydroxy-vitamin D in tuberculosis patients were not statistically different from the levels of serum 25 hydroxy-vitamin D in healthy controls. However, among patients with pulmonary tuberculosis, there was a significant negative correlation between the levels of serum 25 hydroxy-vitamin D and levels of sputum positivity. Conclusion: Serum vitamin D levels negatively correlates with bacterial load in patients with active pulmonary tuberculosis.

      • KCI등재

        Structural, Impedance and Modulus Studies of Effect of Magnesium (Mg) Substitution on Spinel Li4Ti5O12 Anode Materials

        B. Vikram Babu,M. Sushma Reddi,A. Rama Krishna,B. Sathish Mohan,G. Chandana,K. Anjani Devi,B. Sridhar,K. Samatha 한국전기전자재료학회 2022 Transactions on Electrical and Electronic Material Vol.23 No.5

        This research article aims at reporting the influence of magnesium by studying the structural, electrical impedance and modulus properties of the Mg substituted Li 4 Ti 5 O 12 . These studies are useful for the electrochemical properties. The XRD reveals that the structure of all the Mg substituted materials belongs to the cubic spinel group having Fd-3m space symmetry. SEM images display the structural, morphological properties with the average size of grains falling in the vicinity of 1 μm. The electrical impedance of Li 4− x Mg x Ti 5 O 12 materials was analyzed at frequencies between 20 Hz and 1 MHz and in the 30–120 °C range of temperature by employing the complex impedance spectroscopy (CIS) method. The modulus formalism is also a suitable tool to understand the dynamical characteristics of electrical transport phenomena. The complex electric modulus spectrum signifi es quantifying the allocation of ion energies or confi gurations in the lattice. Also, it portrays the electrical relaxation of ion-conducting lattices as a feature of materials at a minuscule level. The obtained results of substitution of Mg in Li 4 Ti 5 O 12 anode materials improve the potential applications of conductivity and charge/discharge performance.

      • KCI등재

        X-ray / gamma ray radiation shielding properties of a-Bi 2 O 3 synthesized by low temperature solution combustion method

        B. Chinnappa Reddy,H.C. Manjunatha,Y.S. Vidya,K.N. Sridhar,U. Mahaboob Pasha,L. Seenappa,B. Sadashivamurthy,N. Dhananjaya,K.V. Sathish,P.S. Damodara Gupta 한국원자력학회 2022 Nuclear Engineering and Technology Vol.54 No.3

        In the present communication, pure and stable a-Bismuth Oxide (Bi2O3) nanoparticles (NPs) weresynthesized by low temperature solution combustion method using urea as a fuel and calcined at 500oC. The synthesized sample was characterized by using powder X-ray Diffraction (PXRD), Scanning ElectronMicroscopy (SEM), Energy dispersive X-ray analysis (EDAX), Transmission Electron Microscopy (TEM),Fourier Transform Infrared Spectroscopy (FTIR) and UVeVisible absorption spectroscopy. The PXRDpattern confirms the formation of mono-clinic, stable and low temperature phase a-Bi2O3. The directoptical energy band gap was estimated by usingWood and Tauc's relation which was found to be 2.81 eV. The characterized sample was studied for X-ray/gamma ray shielding properties in the energy range0.081e1.332 MeV using NaI (Tl) detector and multi channel analyzer (MCA). The measured shieldingparameters agrees well with the theory, whereas, slight deviation up to 20% is observed below 356 keV. This deviation is mainly due to the influence of atomic size of the target medium. Furthermore an accuratetheory is necessary to explain the interaction of X-ray/gamma ray with the NPs.The present workopens new window to use this facile, economical, efficient, low temperature method to synthesizenanomaterials for X-ray/gamma ray shielding purpose

      • KCI등재

        Green synthesis of Lead–Nickel–Copper nanocomposite for radiation shielding

        Chandrika B.M.,Manjunatha Holaly Chandrashekara Shastry,Munirathnam R.,Sridhar K.N.,Seenappa L.,Manjunatha S.,Lourduraj A.J. Clement 한국원자력학회 2023 Nuclear Engineering and Technology Vol.55 No.12

        For the first time Pb, Ni, and Cu nanocomposites were synthesized by versatile solution combustion synthesis using extract as a reducing agent, to study the potential applications in X-ray/gamma, neutron, and Bremsstrahlung shielding. The synthesized Lead–Nickel–Copper (LNC) nanocomposites were characterized by PXRD, SEM, UV–VIS, and FTIR for the confirmation of successful synthesis. PXRD analysis confirmed the formation of multiphase LNC NCs and the Scherrer equation and the W-H plot gave the average crystal sizes of 19 nm and 17 nm. Surface morphology using SEM and EDX confirmed the presence of LNC NCs. Strong absorption peaks were analyzed by UV visible spectroscopy and the direct energy gap is found to be 3.083 eV. Functional groups present in the LNC NCs were analyzed by FTIR spectroscopy. X-ray/gamma radiation shielding properties were measured using NaI(Tl) detector coupled with MCA. It is found to be very close to Pb. Neutron shielding parameters were compared with traditional shielding materials and found LNC NCs are better than lead and concrete. Secondary radiation shielding known as Bremsstrahlung shielding characteristics also studied and found that LNC NCs are best in secondary radiation shielding. Hence LNC NCs find shielding applications in ionizing radiation such as X-ray/gamma and neutron radiation

      • KCI등재

        Synthesis, physical, optical and radiation shielding properties of Barium-Bismuth Oxide Borate-A novel nanomaterial

        Chandrika B.M.,Manjunatha Holaly Chandrashekara Shastry,Sridhar K.N.,Ambika M.R.,Seenappa L.,Manjunatha S.,Munirathnam R.,Lourduraj A.J. Clement 한국원자력학회 2023 Nuclear Engineering and Technology Vol.55 No.5

        Barium Bismuth Oxide Borate (BBOB) has been synthesized for the first time using solution combustion technique. SEM analysis reveal flower shape of the nanoparticles. The formation of the nanoparticles has been confirmed through XRD & FTIR studies which gives the physical and chemical structure of the novel material. The UV light absorption is observed in the range 200e300 nm. The present study highlights the radiation shielding ability of BBOB for different radiations like X/Gamma rays, Bremsstrauhlung and neutrons. The gamma shielding efficiency is comparable to that of lead in lower energy range and lesser than lead in the higher energy range. The bremsstrauhlung exposure constant is comparably larger for BBOB NPs than that of concrete and steel however it is lesser than that of lead. The beauty of BBOB nanoparticles lies in, high absorption of radiations and low emission of secondary radiations when compared to lead. In addition, the neutron shielding parameters like scattering length, absorption and scattering cross sections of BBOB are found to be much better than lead, steel and concrete. Thus, BBOB nanoparticles are highly efficient in absorbing X/Gamma rays, neutrons and bremsstrauhlung radiations

      • SCOPUSKCI등재

        Association of Serum Vitamin D Levels with Bacterial Load in Pulmonary Tuberculosis Patients

        Yuvaraj, B.,Sridhar, M.G.,Kumar, S. Vinod,Kadhiravan, T. The Korean Academy of Tuberculosis and Respiratory 2016 Tuberculosis and Respiratory Diseases Vol.79 No.3

        Background: Vitamin D is known to have diverse effects on various systems in the body. There is evidence to suggest that a link exists between the serum vitamin D status and tuberculosis. The present study was designed to assess the alterations in serum 25-hydroxyvitamin D levels in newly diagnosed sputum acid fast bacilli (AFB) positive pulmonary tuberculosis patients and to study the association, if any, between serum vitamin D levels and different levels of sputum smear positivity. Methods: Serum 25-hydroxyvitamin D levels were estimated in 65 sputum AFB positive pulmonary tuberculosis patients and 65 age and gender-matched healthy controls. Results: The levels of serum 25 hydroxy-vitamin D in tuberculosis patients were not statistically different from the levels of serum 25 hydroxy-vitamin D in healthy controls. However, among patients with pulmonary tuberculosis, there was a significant negative correlation between the levels of serum 25 hydroxy-vitamin D and levels of sputum positivity. Conclusion: Serum vitamin D levels negatively correlates with bacterial load in patients with active pulmonary tuberculosis.

      • KCI등재

        An experimental study on the effect of square grooves on decay characteristics of a supersonic jet from a circular nozzle

        S. Ilakkiya,B. T. N. Sridhar 대한기계학회 2018 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.32 No.10

        In this experimental work, the effect of square grooves on the structure of a supersonic jet emanating from a circular nozzle has been investigated at three different nozzle inlet total pressures i.e 360 kPa, 550 kPa and 720 kPa. The nominal exit Mach number is 1.8. A new empirical relation for predicting the supersonic core length for grooved nozzle has been suggested. Further, a new parameter “groove effectiveness” has also been suggested to quantify the effect of the groove by using the total pressure data in the supersonic core length. Experimental results suggest that at higher nozzle inlet total pressure, the groove effectiveness plays a minor role. From the jet centreline total pressure data, supersonic core length, the locations at which 50 % and 90 % decay occurs have been obtained. It has been observed that higher groove effectiveness is associated with smaller values of supersonic core length, L 50% and L 90% . Schlieren images of the jet structure shows unsymmetrical shock pattern of jets emanating from a single grooved nozzle.

      • KCI등재

        Practical Synthesis of (9S,10R)-9,10-epoxy-(3Z,6Z)-henicosadiene: The Major Pheromone of the Saltmarsh Caterpillar moth Estigmene acrea

        Deepak Kumar,Sridhar Chirumarry,B. V. D. Vijaykumar,S. J. Harshavardhan,장기완,이동하,신동수 대한화학회 2015 Bulletin of the Korean Chemical Society Vol.36 No.4

        An efficient synthesis of (3Z,6Z)-cis-9,10-epoxy-3,6-henicosadiene (1), the major component of sex pheromone of saltmarsh caterpillar moth Estigmene acrea (Drury), was accomplished from commercially available pentadec-3-yn-1-ol and bromoundecane. Chirality was introduced by employing Sharpless asymmetric dihydroxylation on cis-olefin intermediate in the synthesis of 1, for the first time. The other key reactions include metal-dissolving coupling, Lindlar's catalyst-assisted partial hydrogenation, one-pot, three-step epoxidation from vicinal diol, and Wittig olefination. The overall yield of 1 was 24.7% in eight steps. The efficiency and simplicity of this synthesis allow the potential use of pheromone 1 in pest management programs.

      • KCI등재

        Bioresorbable whitlockite coatings on titanium by EPD for biomedical applications

        S.P. Vinodhini,B. Venkatachalapathy,T.M. Sridhar 한양대학교 세라믹연구소 2016 Journal of Ceramic Processing Research Vol.17 No.9

        We have developed biodegradable tri calcium phosphate [Ca3(PO4)2 , β-TCP (whitlockite)] coatings on titanium by surfacemodification to improve the corrosion resistance and biocompatibility. It is a bioresorbable biomaterial and is absorbed forthe formation of new bone tissues. Nano whitlockite powder was synthesized by wet chemical precipitation method and coatedon titanium surfaces by electrophoretic deposition (EPD) from a 1.5% suspension in ethanol. The coatings were carried outat various potentials ranging from 10-50 V and were followed by sintering in vacuum at 800 oC for 1 hr. The crystallinity,vibrational states, surface morphology and composition of the coatings were characterized by XRD, FTIR, and FE-SEM withEDAX respectively. The corrosion resistance of the coating was further evaluated electrochemically to study the stability of thecoatings using open circuit potential-time measurements, potentiodynamic polarization studies and impedance behavior in Ringer’ssolution. The electrochemical corrosion parameters evaluated indicate a shift towards noble direction for the whitlockite coatedsamples in comparison with uncoated titanium metal. Electrochemical impedance spectroscopic investigations revealed the stablenature of the coatings formed. In vitro cytotoxicity studies of the coated material were carried out by MTT assay. The stable natureof the cells confirms the biocompatibility of whitlockite coatings on the titanium substrate.

      • KCI등재

        X-ray/gamma radiation shielding properties of Aluminium-Barium Zinc Oxide nanoparticles synthesized via low temperature solution combustion method

        Sathish K.V.,Sridhar K.N.,Seenappa L.,Manjunatha H.C.,Vidya Y.S.,Chinnappa Reddy B.,Manjunatha S.,Santhosh A.N.,Munirathnam R.,Raj Alfred Cecil,Damodara Gupta P.S.,Sankarshan B.M. 한국원자력학회 2023 Nuclear Engineering and Technology Vol.55 No.5

        For the first time Aluminium-BariumeZinc oxide nanocomposite (ZABONC) was synthesized by solution combustion method where calcination was carried out at low temperatures (6000 C) to study the electromagnetic (EM) (X/g) radiation shielding properties. Further for characterization purpose standard techniques like PXRD, SEM, UV-VISIBLE, FTIR were used to find phase purity, functional groups, surface morphology, and to do structural analysis and energy band gap determination. The PXRD pattern shows (hkl) planes corresponding to spinel cubic phase of ZnAl2O4, cubic BaðNO3Þ2, a and g phase of Al2O3 which clearly confirms the formation of complex nano composite. From SEM histogram mean size of nano particles was calculated and is in the order of 17 nm. Wood and Tauc’s relation direct energy band gap calculation gives energy gap of 2.9 eV. In addition, EM (X/g) shielding properties were measured and compared with the theoretical ones using standard procedures (NaI (Tl) detector and multi channel analyzer MCA). For energy above 356 keV the measured shielding parameters agree well with the theory, while below this value slight deviation is observed, due to the influence of atomic/crystallite size of the ZABONC. Hence synthesized ZABONC can be used as a shielding material in EM (X/g) radiation shielding

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