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        Black phosphorus nanosheets‑based effective electrochemical sensor for uric acid detection

        Hao Wang,Haitao Wang,Jingjing Yang,Pramitha Yuniar Diah Maulida,Jing Zou,Arramel,Can Wu,Jizhou Jiang 한국탄소학회 2023 Carbon Letters Vol.33 No.7

        Black phosphorus (BP) is incorporated in the electrochemical detection of uric acid (UA) to form few layers of BP nanosheets (BPNS)-modified glassy carbon electrodes (BPNS/GCE), investigated by means of ultrasound-assisted liquid-phase exfoliation. We find a significant increase in the peak current magnitude and positive potential shift in the electrochemical response of BPNS/GCE, which may be attributed to the larger specific surface area and good charge transfer ability of BPNS. Further, the electrochemical response of BPNS/GCE is evaluated under different conditions to achieve the optimal conditions. UA detection using differential pulse voltammetry (DPV) shows linear response within the range of 1–1000 μM with a detection limit of 0.33 μM. This work reveals new applications of BP nanomaterials in the electrochemical sensing, thereby promoting further advancement in terms of practical applications of two-dimensional nanomaterials.

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        TiO2 nanoparticles anchored on graphene oxide nanosheets as a highly active photocatalyst for decabromodiphenyl ether degradation

        Man Yang,Yilun Zou,Lei Ding,Yang Yu,Jinai Ma,Lei Li,Ande Fudja Rafryanto,Jing Zou,Arramel,Haitao Wang 한국탄소학회 2023 Carbon Letters Vol.33 No.5

        Decabromodiphenyl ether (BDE209) is a persistent aromatic compound widely associated with environmental pollutants. Given its persistence and possible bioaccumulation, exploring a feasible technique to eradicate BDE209 efficiently is critical for today’s environmentally sustainable societies. Herein, an advanced nanocomposite is elaborately constructed, in which a large number of titanium dioxide ( TiO2) nanoparticles are anchored uniformly on two-dimensional graphene oxide (GO) nanosheets ( TiO2/GO) via a modified Hummer’s method and subsequent solvothermal treatment to achieve efficient photocatalytic degradation BDE209. The obtained TiO2/ GO photocatalyst has excellent photocatalytic due to the intense coupling between conductive GO nanosheets and TiO2 nanoparticles. Under the optimal photocatalytic degradation test conditions, the degradation efficiency of BDE209 is more than 90%. In addition, this study also provides an efficient route for designing highly active catalytic materials.

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        Modulation of the lattice structure of 2D carbon‑based materials for improving photo/electric properties

        Fangyi Li,Yulianti Anjarsari,Jiamei Wang,Rifda Azzahiidah,Jizhou Jiang,Jing Zou,Kun Xiang,Huijuan Ma,Arramel 한국탄소학회 2023 Carbon Letters Vol.33 No.5

        Reliable, inexpensive, environment-friendly, and durable properties of carbon materials with unique and outstanding photoelectric performance is highly desired for myriad of applications such as catalysis and energy storage. Since lattice modulation is a vital method of surface modification of materials, which form by an external force during the synthesis process, causing the internal compression and stretching, leading to lattice sliding event. In this review, we present a summary of different methods to tailor the lattice modulation in 2D carbon-based materials, including grain/twin boundary, lattice strain, lattice distortion, and lattice defects. This overview highlights the implication control of the diverse morphologies of nanocrystals and how to tailor the materials properties without adding any polymers. The improvement in the performance of 2D carbon materials ranges from the enhancement of charge transport and conductivity, structural stability, high-performance of light absorption capacity, and efficient selectivity promote the future prospect of 2D carbon materials broaden their applications in terms of energy conversion and storage. Finally, some perspectives are proposed on the future developments and challenges on 2D carbon materials towards energy storage applications.

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        Recent advances of MXenes Mo2C‑based materials for efficient photocatalytic hydrogen evolution reaction

        Jiamei Wang,Qin Qin,Fangyi Li,Yulianti Anjarsari,Wei Sun,Rifda Azzahiidah,Jing Zou,Kun Xiang,Huijuan Ma,Jizhou Jiang,Arramel 한국탄소학회 2023 Carbon Letters Vol.33 No.5

        The emergence of Mo2C- based catalysts in recent years has been favored as promising contender within diverse class MXenes. In terms of rapid development in the photocatalytic application, these intriguing compounds exhibit excellent photocatalytic performance because of their superior optical properties and peculiar structure characteristics. Unfortunately, a systematic review of Mo2C- based catalysts is lacking. In this review, we abstract the implication of structure—property relationship of emerging Mo2C- based MXenes materials and their applications toward the photocatalytic hydrogen evolution reaction (HER). Furthermore, synthetic pathways to prepare high-quality, low cost Mo2C- based MXenes materials and their outcomes for high HER applications are systematically described. Finally, several insights are provided into the prospects and future challenges for the development of highly reactive Mo2C- based MXenes materials, which present large range opportunities in this promising 2D materials for green and clean energy in environmental fields. This review provides a comprehensive scientific guide to the preparation, modification, and photocatalytic HER of MXenes-based materials.

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