http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Musselwhite, Nathan,Na, Kyungsu,Sabyrov, Kairat,Alayoglu, Selim,Somorjai, Gabor A. American Chemical Society 2015 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - Vol.137 No.32
<P>Several types of mesoporous aluminosilicates were synthesized and evaluated in the catalytic isomerization of <I>n</I>-hexane, both with and without Pt nanoparticles loaded into the mesopores. The materials investigated included mesoporous MFI and BEA type zeolites, MCF-17 mesoporous silica, and an aluminum modified MCF-17. The acidity of the materials was investigated through pyridine adsorption and Fourier Transform-Infrared Spectroscopy (FT-IR). It was found that the strong Brönsted acid sites in the micropores of the zeolite catalysts facilitated the cracking of hexane. However, the medium strength acid sites on the Al modified MCF-17 mesoporous silica greatly enhanced the isomerization reaction. Through the loading of different amounts of Pt into the mesopores of the Al modified MCF-17, the relationship between the metal nanoparticles and acidic sites on the support was revealed.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jacsat/2015/jacsat.2015.137.issue-32/jacs.5b04808/production/images/medium/ja-2015-04808g_0008.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ja5b04808'>ACS Electronic Supporting Info</A></P>
Bernardi, F.,Grass, M.E.,Hong, Y.P.,Chang, R.,Jabeen, N.,Zhang, C.,Eichhorn, B.W.,Seo, B.,Alayoglu, S.,Hussain, Z.,Joo, S.H.,Liu, Z. Elsevier Science Publishers 2016 CATALYSIS TODAY - Vol.260 No.-
<P>Rh0.5Pd0.5/CeO2 bimetallic nanoparticles were subjected to reducing and oxidizing atmospheres at different temperatures and characterized by means of the Ambient Pressure X-Ray Photoelectron Spectroscopy (AP-XPS). The surface atomic population is calculated for all cases. By using a high temperature pretreatment at 480 degrees C in H-2 atmosphere, it was possible to control the surface atomic population with Pd atoms frozen at the skin layer even in an oxidizing atmosphere, which is not observed without high temperature pre-treatment (Rh atoms at the skin layer). The change of the Rh/Pd surface segregation behavior after the high temperature pre-treatment is attributed to the geometrical factor of Strong Metal Support Interaction (SMSI) effect, i.e., the occurrence of the ceria capping layer around nanoparticles. (C) 2015 Elsevier B.V. All rights reserved.</P>