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Triglyceride의 洗滌性에 關한 硏究 : 基質의 影響 Correlating the substrates
鄭惠嫄 한국의류학회 1984 한국의류학회지 Vol.8 No.1
The effects of Temperature on the removal of triglyceride were studied with soaps having various chain lengths of alkyl group. Cellophane, polyester film and alkali-treated polyester film were soiled with tripalmitin, tagged with C^14, and detergency was evaluated by analysing the tripalmitine on the fabric before and after washing by means of liquid scintillation counting. The results were as following: 1) Triglyceride was completely removed from cellophane in distilled water without surfactant at any temperature, because of the hydrophillic nature of cellulose. The detergency of triglyceride from polyester film fully depended on the state of tripalmitin. The detergency of alkali treated polyester film was better than that of untreated polyester film at lower temperature due to increased hydrophilicity, but worse at higher temperature due to the diffusion of molten tripalmitin into the grooves, formed by alkali treatment. 2) The detergency from polyester film was increased with elevating temperature and after reaching some optimum detergencies, the detergencies were rather decreased with increasing temperature. The temperatures of optimum detergency were shifted to higher with increasing chain length of alkyl group. 3) When the soiled film was baked at 60℃ and 70℃ for 20 min, the detergency vs. temperature was much the same as the case of without-baking. These results indicate that the detergency of triglyceride was largely correlated with the suspending power of surfactants at low temperature and with state of soil and hydrophilicity of substrates with elevating temperature.
정혜원,유화숙 한국의류학회 2003 한국의류학회지 Vol.27 No.9,10
Following a treatment with edible oils and/or washing, the tensile properties of vulcanized rubber were measured to assess the effect of the sorbed edible oil. Rubber soiled with soybean oil, after 8 weeks stroage in a 30℃ incubator, retained 61% of its original strength, and rubber soiled and washed retained the 73%. The strength of the rubber soiled with oil decreased remarkably during the first 2 weeks. After repeating this soiling and/or washing 7 times, the soiled rubber had only 16% of its original strength, the rubber soiled and washed had 45%. In all cases, breaking elongations were not decreased as much as tensile strength; therefore, more of the elasticity of the rubber remained than did the strength. From these results it is concluded that washing after soiling with oils is very helpful in maintaining the strength of rubber. In this study, three different surfactant solutions, AS, AE and AS/AE, were used. In the AS solution, the contact angle of the soybean oil was greater and the work of the detergency was the smaller than in either the AE or the AS/AE solution, the loss of the strength of the rubber washed in AS solution did not decrease significantly. These results suggest that rolling-up, emulsification and solubilization also participat in the removal of oil from rubber.