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Poly-β(1,4)-D-glucosamine-g-polyethyleneoxide의 합성 및 물성에 관한 연구
주상명,장광태,성용길 동국대학교 자연과학연구원 1995 자연과학연구 논문집 Vol.15 No.-
Poly-β(1,4)-D-glucosamine derived from poly-β(1,4)-N-acetyl-D-glucosamine by treating with alkaline solution has been reported to be a promising polymer not only in the chemical field but also in biomedical area. Poly-β(1,4)-D-glucosamine used in this experiment was seen about 93 percentage of degree of deacetylation by heterogeneous alkaline soultion. Poly-β(1,4)-D-glucosamine-g-polyethyleneoxide was synthesized by homogeneous method. Various molecular weights of polyethyleneoxide as a hydrophilic and flexible spacer were introduced to Poly-β(1,4)-D-glucosamine to produce Poly-β(1,4)-D-glucosamine-g-polyethyleneoxide. The synthesized copolymers are characterized by FT-IR, elemental analysis, thermogravimetric analyzer, and differential scanning calorimetry.