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박소진,( Manju Rani ),( Rekha Devi ),( Sanjeev Markin ) 한국공업화학회 2019 한국공업화학회 연구논문 초록집 Vol.2019 No.0
Experimentally measured data of various thermophysical properties of possible mixtures containing oxygenates and components of gasoline such as alkanes, aromatics over a wide temperature range, is very helpful for formulation of environmental friendly fuel, petrochemical additives. In this work, Density and refractive indices of the binary and ternary liquid mixtures of diisopropyl ether, benzene and n-hexane were experimentally measured from 298.15 K to 318.15 K over the entire composition range. Excess molar volume and deviation in refractive index of binary and ternary mixtures were fitted to the Redlich-Kister equation and the Singh equation respectively. The excess volume data of binary and ternary mixtures have also been interpreted using Prigogine-Flory-Patterson theory. Various mixing rules were used for theoretical determination of refractive indices of the binary and ternary mixtures. Temperature effects were also studied in terms of molecular interactions.