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Yunong Li,Dening Zou,Wanwan Chen,Yingbo Zhang,Wei Zhang,Fanghong Xu 대한금속·재료학회 2022 METALS AND MATERIALS International Vol.28 No.8
To study and understand the solidification behavior of super austenitic stainless steel under different cooling rates and segregationlaws of alloying elements is of great significance to optimize the subsequent diffusion annealing homogenizationtreatment process and improve product quality. According to Thermo-Calc thermodynamic simulation results and combinedwith high temperature laser confocal scanning electron microscope (HT-CSLM), the tissue morphology of 904L superaustenitic stainless steel was observed in-situ during solidification. The solidification path of the test steel was determinedvia calculation with the Scheil-Gulliver model. Microscopy techniques, including true color microscopy, scanning electronmicroscopy (SEM), energy dispersive spectrometer (EDS), and electron probe microanalyzer (EPMA) were used to analyzethe influence of different cooling rates (6 ℃/min, 50 ℃/min, and 100 ℃/min) on the solidification structure and determine themain distribution law of alloying elements. This analysis determined that the solute distribution coefficient (K) of Cr, Mn,Mo, Cu, and Si elements is less than 1 during the solidification process, which means that they will accumulate in the liquidphase. Among them, elemental Mo segregation is the most severe, while elemental Ni hardly segregates. As the cooling rateincreases, the crystallization temperature of the test steel decreases, and the secondary dendrite arm spacing λ2 decreases,the concentration of Mo in the residual liquid phase increases.
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Miaomiao Li,Dening Zou,Yunong Li,Libo Tong 대한금속·재료학회 2023 METALS AND MATERIALS International Vol.29 No.3
904L super austenitic stainless steel is prone to harmful secondary phase precipitation, which reduces corrosion resistance. The cooling rate during the solidification of steel is one of the critical factors affecting the precipitation of brittle phases instainless steel metals. In this paper, the effect of the cooling rates (6, 50, 100, 500, and 1000 °C min−1) on the initial corrosionbehavior of 904L steel in a simulated flue gas desulfurization (FGD) solution was studied by electrochemical measurementsand microscopic morphology observation. The results show that as the cooling rates increases, the primary solidification temperatureand the secondary dendrite arm spacing decrease. The precipitated phase in the steel is a σ-phase mainly distributedinterdendrites and forms zones of chromium and molybdenum depletion, reducing pitting resistance. With the increase in thecooling rate, the corrosion resistance increases first and then decreases, and reaches the maximum at 100 °C min−1. At thesame time, different cooling rates result in different contents of Cr and Mo in σ phase. At 100 °C min−1, the concentrationgradient of Cr and Mo near the interdendrites is the lowest compared with other cooling rates, which inhibits the growthrate of the σ phase nuclei and produces a more uniform microstructure. Corrosion test results show that pitting corrosion issensitive to the increase in the contents of Cr and Mo in the σ phase. The higher the content of Cr and Mo in the σ phase, themore serious the depletion of Cr and Mo near the interdendrites, and the worse the corrosion resistance.
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Miaomiao Li,Miaomiao Li,Dening Zou,Yunong Li,Libo Tong1 대한금속ᆞ재료학회 2023 METALS AND MATERIALS International Vol.29 No.2
904L super austenitic stainless steel is prone to harmful secondary phase precipitation, which reduces corrosion resistance. The cooling rate during the solidification of steel is one of the critical factors affecting the precipitation of brittle phases instainless steel metals. In this paper, the effect of the cooling rates (6, 50, 100, 500, and 1000 °C min−1) on the initial corrosionbehavior of 904L steel in a simulated flue gas desulfurization (FGD) solution was studied by electrochemical measurementsand microscopic morphology observation. The results show that as the cooling rates increases, the primary solidification temperatureand the secondary dendrite arm spacing decrease. The precipitated phase in the steel is a σ-phase mainly distributedinterdendrites and forms zones of chromium and molybdenum depletion, reducing pitting resistance. With the increase in thecooling rate, the corrosion resistance increases first and then decreases, and reaches the maximum at 100 °C min−1. At thesame time, different cooling rates result in different contents of Cr and Mo in σ phase. At 100 °C min−1, the concentrationgradient of Cr and Mo near the interdendrites is the lowest compared with other cooling rates, which inhibits the growthrate of the σ phase nuclei and produces a more uniform microstructure. Corrosion test results show that pitting corrosion issensitive to the increase in the contents of Cr and Mo in the σ phase. The higher the content of Cr and Mo in the σ phase, themore serious the depletion of Cr and Mo near the interdendrites, and the worse the corrosion resistance.
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Ubiquitin D Promotes Progression of Oral Squamous Cell Carcinoma via NF-Kappa B Signaling
Song, An,Wang, Yi,Jiang, Feng,Yan, Enshi,Zhou, Junbo,Ye, Jinhai,Zhang, Hongchuang,Ding, Xu,Li, Gang,Wu, Yunong,Zheng, Yang,Song, Xiaomeng Korean Society for Molecular and Cellular Biology 2021 Molecules and cells Vol.44 No.7
Ubiquitin D (UBD) is highly upregulated in many cancers, and plays a pivotal role in the pathophysiological processes of cancers. However, its roles and underlying mechanisms in oral squamous cell carcinoma (OSCC) are still unclear. In the present study, we investigated the role of UBD in patients with OSCC. Quantitative real-time polymerase chain reaction and Western blot were used to measure the expression of UBD in OSCC tissues. Immunohistochemistry assay was used to detect the differential expressions of UBD in 244 OSCC patients and 32 cases of normal oral mucosae. In addition, CCK-8, colony formation, wound healing and Transwell assays were performed to evaluate the effect of UBD on the cell proliferation, migration, and invasion in OSCC. Furthermore, a xenograft tumor model was established to verify the role of UBD on tumor formation in vivo. We found that UBD was upregulated in human OSCC tissues and cell lines and was associated with clinical and pathological features of patients. Moreover, the overexpression of UBD promoted the proliferation, migration and invasion of OSCC cells; however, the knockdown of UBD exerted the opposite effects. In this study, our results also suggested that UBD promoted OSCC progression through NF-κB signaling. Our findings indicated that UBD played a critical role in OSCC and may serve as a prognostic biomarker and potential therapeutic target for OSCC treatment.
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