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RISS 인기검색어
- 검색키워드
- 저자 : Xue J. Huo (검색결과 2 건)
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Xue, X.,Fan, B.,Liu, T.,Sun, X.,Huo, L.,Ha, S.,Choi, H.,Kim, T.,Kim, J.,Wei, D. Royal Society of Chemistry 2016 Polymer chemistry Vol.7 No.24
<P>Extensive efforts have been focused on the study of wide-band gap (WBG) polymers due to their important applications in multiple junction and ternary blend organic solar cells. Herein, three WBG copolymers named PBDT(X)-T1 (X = O, S, Se) were synthesized based on the benzodithiophene (BDT) donor unit and 1,3-bis(5-bromothiophen-2-yl)-5,7-bis(2-ethylhexyl)-4H, 8H-benzo[1,2-c: 4,5-c']dithiophene-4,8-dione (T1) acceptor unit. Different aromatic heterocycle groups (furan, thiophene and selenophene) were introduced to modify the BDT unit to investigate the influence of conjugated side chains on the photovoltaic properties of conjugated polymers. Photophysical properties, electrochemistry, charge transport and crystalline properties of the polymers were studied to discuss the role of chalcogen atoms on the performance of conjugated polymers. Solar cells based on these three WBG copolymers were fabricated. Among them, the PBDT(Se)-T1-based solar cell shows the best photovoltaic performance with the highest power conversion efficiency (PCE) of 8.52%, an open-circuit voltage (V-oc) of 0.91 V, and a high fill factor (FF) of 72%. The high crystallinity and preferential face-on orientation in the blend film partially explain the superior photovoltaic performance achieved in PBDT(Se)-T1-based solar cells. The results indicate the important role of chalcogen atoms in conjugated side chains and that high photovoltaic performance can be realized through side chain engineering of BDT-based WBG conjugated polymers.</P>
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Experimental and numerical study on large-curvature curved composite box girder under hogging moment
Li Zhu,Jia J. Wang,Guan Y. Zhao,Xue J. Huo,Xuan Li 국제구조공학회 2020 Steel and Composite Structures, An International J Vol.37 No.2
Curved steel-concrete composite box girder has been widely adopted in urban overpasses and ramp bridges. In order to investigate its mechanical behavior under complicated and combined bending, shear and torsion load, two large-curvature composite box girders with interior angles of 25º and 45º were tested under static hogging moment. Based on the strain and deflection measurement on critical cross-sections during the static loading test, the failure mode, cracking behavior, load-displacement relationship, and strain distribution in the steel plate and rebar were investigated in detail. The test result showed the large-curvature composite box girders exhibited notable shear lag in the concrete slab and steel girder. Also, the constraint torsion and distortion effect caused the stress measured at the inner side of the composite beam to be notably higher than that of the outer side. The strain distribution in the steel web was approximately linear; therefore, the assumption that the plane section remains plane was approximately validated based on strain measurement at steel web. Furthermore, the full-process non-linear elaborate finite element (FE) models of the two specimens were developed based on commercial FE software MSC.MARC. The modeling scheme and constitutive model were illustrated in detail. Based on the comparison between the FE model and test results, the FE model effectively simulated the failure mode, the load-displacement curve, and the strain development of longitudinal rebar and steel girder with sufficient accuracy. The comparison between the FE model and the test result validated the accuracy of the developed FE model.
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