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Laccase-Mediated In Situ Oxidation of Dopamine for Dyeing of Human Hair
Weini Jia,Shirong Li,Zhengxin Luo,Hainan Yu,Wenjun Zhu,Wenjun Zhu,Qing-hui Mao,Xiaoli Zhang,Zhi-jie Liang,Aixue Dong 한국섬유공학회 2021 Fibers and polymers Vol.22 No.1
Due to the damage of scalp because of chemical dyes, increasing attention had been paid to the ecological dyeingof human hair. To address the need for ecological restoration and dyeing of human hair, herein, a novel approach has beenproposed via laccase-mediated in situ oxidation of dihydroxy phenylalanine (dopamine). As laccase can catalyze dopamineoxidation and then polymerization to produce strongly colored polymers, different biological coloration processes of humanhair based on this process were investigated: (i) Human hair was treated with laccase alone; (ii) The absorption of human hairwith dopamine, followed by further catalysis of air; (iii) The absorption of human hair with dopamine, followed by furthercatalysis of laccase; (iv) Simultaneous laccase-mediated polymerization and dyeing of human hair; and (v) Polymerization ofDopamine with laccase and then dyeing human hair. The surface properties of dyed hair were evaluated in terms of ultraviolet(UV)-protection, color fastness, Fourier transforming infrared spectrum (FT-IR), optical microscope, and scanning electronmicroscopy (SEM). The results show that best hair dyeing effect was achieved via simultaneous laccase-mediatedpolymerization and dyeing. The dyed hair obtained K/S values of 28, light fastness of level 5, and UPF of 100+. The opticalmicroscope and SEM observations show that the surface of colored hair fibers was covered with thin burrs, which can beattributed to polydopamine attached with physical adhesive force and covalent reaction. FT-IR analysis shows that functionalgroups were present on the surface of the dyed hair which can be considered as introduction of hydroxyl radical groups. Thisbiological stain technique may be widely used in dyeing of hair with black color.
Mechanism and Analysis of Laccase-mediated Coloration of Silk Fabrics
Weini Jia,Qiang Wang,Xuerong Fan,Aixue Dong,Yuanyuan Yu,Ping Wang 한국섬유공학회 2018 Fibers and polymers Vol.19 No.4
Laccase provides a mild and eco-friendly alternative for the dyeing of fabrics. In this study, laccase-mediated catalytic oxidation was employed in coloration of silk fabrics, and the color was then assessed. The surfaces of silk fabrics were characterized by scanning electron microscope (SEM), atomic force microscopy (AFM), attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), and X-ray photoelectron spectroscopy (XPS). Their thermal and crystallization properties were also investigated by differential scanning calorimetry (DSC), thermogravimetry (TG), and Xray diffraction (XRD). The textile softness was evaluated by the bending rigidity (B). In addition, high performance liquid chromatography (HPLC) and ultraviolet-visible (UV-VIS) spectroscopy were employed to analyze hydrolysate of silk fabrics obtained from hydrolysis with hydrochloric acid solution. The results demonstrated that a stable reddish-yellow layer was formed on the surface of silk fabrics by the laccase-mediated coupling of phenol hydroxyl side chains in the silk polypeptide. Moreover, the SEM and AFM observations showed that the surface of colored silk fiber was slick. ATR-FTIR and XPS results demonstrated differences in the C, N, O contents and the functional groups of the uncolored and colored silk fabrics. The DSC, TG, and XRD indicated that the thermal properties of silk fabrics were not affected by laccase and the coupling reaction mainly occurred in the amorphous region. The DMF extraction test further illustrated that covalent bonds were formed between tyrosine residues constituent of silk peptides. Finally, HPLC and UV-VIS results showed that new substances were formed as a result of conjugation between benzene rings.
Zhi-jie Liang,Jiayu Peng,Jiale Liang,Yujing Song,Weini Jia,Qing-hui Mao 한국섬유공학회 2022 Fibers and polymers Vol.23 No.12
The outstanding redox chemistry of polyoxovanadate has shown excellent catalysis prospects. In the present work,the effect of polyoxovanadate (K7[MnV13O38]·18H2O) on the catalytic polymerization of catechol was investigated for thefirst time. The synthesized polymer was applied in-situ for the dyeing of cotton under mild conditions. Various processparameters, including the dosages of catechol and polyoxovanadate and incubation temperature, which influence the colordepth, were analyzed. The effect of different time intervals on polyoxovanadate-catalyzed polymerization of catechol wasexamined using UV-vis spectroscopy. The color intensity of cotton was evaluated by means of K/S value and color difference(ΔE*). The results show that the dyeing depth of the dyed cotton fabrics gradually increased with the extension of time andthe increase in the concentration of polyoxovanadate. This work represents a novel synthetic process exploring the potentialof a polymer to be used for textile dyeing.