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        Few-layered graphene oxides as superior adsorbents for the removal of Pb(II) ions from aqueous solutions

        Wenbao Jia,Songsheng Lu 한국화학공학회 2014 Korean Journal of Chemical Engineering Vol.31 No.7

        Few-layered graphene oxides (GOs) were successfully synthesized from graphite using Hummers’ method. The synthesized GOs were characterized in detail by SEM, AFM, XRD, and FTIR spectroscopy. The prepared GOswere used as adsorbents to preconcentrate Pb(II) ions from large volumes of aqueous solutions. The effects of pH, ionicstrength and temperature on the removal of Pb(II) ions from solution to GOs were investigated. The sorption of Pb(II)on GOs was dependent on pH values and independent of ionic strength, which suggested that Pb(II) sorption on GOswas mainly dominated by strong inner-sphere surface complexation. The maximum adsorption capacities (Csmax) ofPb(II) on GOs were calculated to be 344 mg/g at 293 K, 487 mg/g at 308 K, and 758mg/g at 333 K, respectively. TheCsmax values are the highest sorption capacities of today’s materials for the sorption of Pb(II) ions from aqueous solutions. The thermodynamic parameters were calculated from the temperature-dependent sorption isotherms, and the resultsindicated that Pb(II) sorption on GOs was spontaneous and endothermic. The results suggested that the GOs were promisingmaterials for the preconcentration of Pb(II) and other kinds of heavy metal ions from aqueous solutions in environmentalpollution cleanup in real work.

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