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Fenghong Huang,Renmin Gong,Na Li,Shoujun Ni,Pingzhen Guo 한국화학공학회 2010 Korean Journal of Chemical Engineering Vol.27 No.5
An ion exchanger with carboxyl groups as active sites was prepared by activating sawdust with epichlorohydrin,followed by coupling the epoxy-activated sawdust with aspartic acid. The optimal sorption condition, sorption capacity, kinetics and thermodynamics of basic dyes on sawdust ion exchanger (SIE) from aqueous solution were investigated in a batch system. Two basic dyes, methylene blue (MB) and crystal violet (CV), were selected as sorbates. The optimal pH value of MB and CV solutions for favorable sorption was pH 4 and above. The removal ratios of MB and CV on SIE increased with increasing sorbent dose but decreased with increasing dye concentration. The isothermal data of MB and CV sorbed on SIE correlated basically with the Langmuir model. The maximum sorption capacity (Qm) of SIE for MB and CV was 222.22 and 232.56 mg/g, respectively. The sorption equilibriums of MB and CV on SIE were reached at about 9 h, and the sorption processes could be described by the pseudo-second-order kinetic model. The thermodynamic study indicated that the sorptions of MB and CV on SIE were spontaneous and endothermic at the predetermined temperatures. High temperatures were favorable for the sorption processes.
Soybean hull functionalized by phosphoric acid for sorption of copper from aqueous solution
Renmin Gong,Lingling Liu,Min Feng,Jiajing Zhao,Xingyan Liu,Shoujun Ni 한국화학공학회 2009 Korean Journal of Chemical Engineering Vol.26 No.2
One kind of potentially biodegradable cationic sorbent, which bears hydroxyl groups of phosphoric acid as its functional groups, with high sorption capacity of copper was prepared by thermochemically esterifying phosphoric acid (PA) onto soybean hull. Sorption of Cu(Ⅱ) from aqueous solution onto modified soybean hull (MSH) was investigated in a batch system. The sorption experiments were performed under various conditions such as different initial pH, copper concentration, MSH dosage, and contact time. The maximum copper sorption was obtained when initial solution pH≥3.5. The isothermal data of copper sorption fitted the Langmuir model and the sorption process could be described by the pseudo-first-order kinetic model. The maximum sorption capacity (Qm) of MSH for Cu(Ⅱ) was 31.55 mg/g. For 100 mg/l of Cu(Ⅱ) solution, a sorption ratio above 91% could be achieved by 5.0 g/l of MSH. The equilibrium of Cu(Ⅱ) sorption was reached within 50 min. The foreign cation and chelator in Cu(Ⅱ) solution caused decline of Cu(Ⅱ) sorption.