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RISS 인기검색어
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- 저자 : Saltiel, Jack (검색결과 5 건)
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2,5-Dimethyl-2,4-hexadiene induced photodechlorination of 9,10-dichloroanthracene
Saltiel, J.,Smothers, W.K.,Schanze, K.S.,Charman, S.A.,Bonneaub, R. Korean Society of Photoscience 2009 Photochemical & photobiological sciences Vol.8 No.6
Photochemical formation of 9-chloroanthracene (MCA) from 9,10-dichloroanthracene (DCA) is observed in the presence of 2,5-dimethyl-2,4-hexadiene (DMH) in acetonitrile (AN). The mechanism of the reaction was investigated using kinetics, deuterium labeling, and quenching techniques. Contrary to conclusions in a recent publication, our work supports the salient features of the mechanism we had proposed earlier. DCA is photostable in degassed AN in the absence of DMH. When DMH is added, irradiation of DCA at 365 or 404 nm converts it quantitatively to MCA. The photoreaction is strongly inhibited when low concentrations of molecular oxygen or 1,2,4,5-tetracyanobenzene are also present. Results from fluorescence quenching studies along with kinetics parameters from the dependence of DCA loss and MCA formation quantum yields on [DMH] implicate participation of the DCA/DMH singlet exciplex, the DCA/$(DMH)_2$ triplex and the DCA radical anion ($DCA^{{\cdot}-}$) as intermediates in the photodechlorination. Results from experiments using deuterated DMH, deuterated AN, and AN containing $D_2O$ or $H_2O$ show that the 10-H of MCA is introduced by protonation of $DCA^{{\cdot}-}$. Contrary to a recent report, there is no radical pathway to MCA via dissociation of $DCA^{{\cdot}-}$ to chloride and $MCA^{\cdot}$ radical. Changes in the absorption spectrum of DCA in AN with increasing [DMH] suggest that the static quenching of DCA fluorescence at high [DMH] is due primarily to nearest neighbour quenching instead of DCA/DMH ground state complex formation.
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Saltiel, David H. Korean Nuclear Society 2007 Nuclear Engineering and Technology Vol.39 No.6
Nuclear energy programs around the world increasingly find themselves at the nexus of potentially conflicting demands from both domestic and international stakeholders. On one side, the rapid growth in demand for electricity coupled with the goal of reducing carbon emissions calls for a significant expansion of nuclear energy. On the other, stakeholders are seeking ever greater safety, environmental, security, and nonproliferation assurances before consenting to the construction of new nuclear energy facilities. Satisfying the demand for clean energy supplies will require nuclear energy operators to find new and innovative ways to build confidence among stakeholders. This paper discusses two related concepts which can contribute to meeting the needs of key stakeholders in cost effective and efficient ways. Structured processes and tools for assessing stakeholder needs can build trust and confidence while facilitating the "designing-in" of information collection systems for new facilities to achieve maximum efficiency and effectiveness. Integrated approaches to monitoring facilities and managing the resulting data can provide stakeholders with continued confidence while offering operators additional facility and process information to improve performance.
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DAVID H. SALTIEL 한국원자력학회 2007 Nuclear Engineering and Technology Vol.39 No.6
Nuclear energy programs around the world increasingly find themselves at the nexus of potentially conflicting demands from both domestic and international stakeholders. On one side, the rapid growth in demand for electricity coupled with the goal of reducing carbon emissions calls for a significant expansion of nuclear energy. On the other, stakeholders are seeking ever greater safety, environmental, security, and nonproliferation assurances before consenting to the construction of new nuclear energy facilities. Satisfying the demand for clean energy supplies will require nuclear energy operators to find new and innovative ways to build confidence among stakeholders. This paper discusses two related concepts which can contribute to meeting the needs of key stakeholders in cost effective and efficient ways. Structured processes and tools for assessing stakeholder needs can build trust and confidence while facilitating the “designing-in” of information collection systems for new facilities to achieve maximum efficiency and effectiveness. Integrated approaches to monitoring facilities and managing the resulting data can provide stakeholders with continued confidence while offering operators additional facility and process information to improve performance.
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Huh Jin Young,Saltiel Alan R. 생화학분자생물학회 2021 Experimental and molecular medicine Vol.53 No.-
Nonalcoholic fatty liver disease (NAFLD) is the most common cause of chronic liver disease and is strongly associated with obesity-related ectopic fat accumulation in the liver. Hepatic lipid accumulation encompasses a histological spectrum ranging from simple steatosis to nonalcoholic steatohepatitis (NASH), which can progress to cirrhosis and hepatocellular carcinoma. Given that dysregulated hepatic lipid metabolism may be an onset factor in NAFLD, understanding how hepatic lipid metabolism is modulated in healthy subjects and which steps are dysregulated in NAFLD subjects is crucial to identify effective therapeutic targets. Additionally, hepatic inflammation is involved in chronic hepatocyte damage during NAFLD progression. As a key immune signaling hub that mediates NF-κB activation, the IκB kinase (IKK) complex, including IKKα, IKKβ, and IKKγ (NEMO), has been studied as a crucial regulator of the hepatic inflammatory response and hepatocyte survival. Notably, TANK-binding kinase 1 (TBK1), an IKK-related kinase, has recently been revealed as a potential link between hepatic inflammation and energy metabolism. Here, we review (1) the biochemical steps of hepatic lipid metabolism; (2) dysregulated lipid metabolism in obesity and NAFLD; and (3) the roles of IKKs and TBK1 in obesity and NAFLD.
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Spectroscopic Evidence for Aggregation of Stilbene Derivatives in Solution
Aguiar, M.,Akcelrud, L.,Pinto, M.R.,Atvars, T.D.Z.,Karasz, F.E.,Saltiel, Jack Korean Society of Photoscience 2003 Journal of Photosciences Vol.10 No.1
The absorption, fluorescence and fluorescence-excitation spectra of concentrated toluene solutions of selected para substituted trans-stilbene derivatives provide strong evidence for aggregation. A red-shifted fluorescence spectrum peaking at 420 nm gains in intensity as the stilbene concentration is increased. The excitation spectrum of this new emission is well to the red of the normal stilbene absorption spectrum, consistent with the appearance of a red shifted shoulder in the UV spectrum. Formation of a fluorescent ground state dimer (or higher aggregate) is proposed to account for these observations. The presence of polar substituents is crucial to the formation of this ground state complex.
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